Skip to main content
SpringerLink
Log in

Action of nucleophilic reagents on compounds of the type [Cl(CH2)nCCl2-]2

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study was made of the action of nucleophilic reagents (KI, KOCOCH3 and NaCN) on hexachloroalkanes of structure [Cl(CH2)nCCl2-]2, in which n = 2, 4, and 6. It was found that hexachlorohexane is inert toward nucleophilic reagents. Hexachlorodecane and hexachlorotetradecane undergo substitution reactions at the chlorines of the chloromethyl groups under the action of nucleophilic reagents.

  2. 2.

    The following compounds were prepared: [I(CH2)4CCl2-]2; [I(CH2)6CCL2; [CH3CO2(CH2)4CCl2]2; [HO(CH2)4CCl2-]2 [NC(CH2)4CCl2-]2; [NC(CH2)6CCl2-]2; [HO2C(CH2)6CCl2-]2; Cl(CH2)4CCl2-CCl2 (CH2)4OCOCH2; Cl(CH2)6CCl2-CCl2(CH2)6I.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature

  1. A. N. Nesmeyanov, R. Kh. Freidlina and L. I. Zakharkin, Proc. Acad. Sci. USSR 96, 87 (1954).

    Google Scholar 

  2. R. Kh. Freidlina and N. A. Semenov, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1957, 466.

  3. British Pat. 652768; C. A. 46, 1577 (1952).

  4. A. N. Nesmeyanov, L. I. Zakharkin and T. A. Kost, Bull. Acad. Sci. USSR, Diva Chem. Sci. 1955, 657.

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR

    R. Kh. Freidlina & T. A. Kost

Authors
  1. R. Kh. Freidlina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. A. Kost
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Freidlina, R.K., Kost, T.A. Action of nucleophilic reagents on compounds of the type [Cl(CH2)nCCl2-]2 . Russ Chem Bull 6, 656–658 (1957). https://doi.org/10.1007/BF01169287

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01169287

Keywords

Search

Navigation