Summary
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1.
Cyclic esters derived from methyl-, chloromethyl-, butyl-, and phenyl-phosphonic acids and ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, and diethylene glycol were synthesized.
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2.
The polymerization of these cyclic phosphoric esters containing five-, six-, seven-, and eight-membered rings was investigated.
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3.
It was shown that cyclic phosphoric esters containing a five-membered ring have the highest tendency to polymerize.
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Korshak, V.V., Gribova, I.A. & Andreeva, M.A. Organophosphorus polymers Communication 1. polymerization of cyclic alkyl- and aryl-phosphonic esters. Russ Chem Bull 6, 641–646 (1957). https://doi.org/10.1007/BF01169283
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DOI: https://doi.org/10.1007/BF01169283