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Interfacial crystallization and electronic properties of platinum double salts

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Abstract

Insoluble platinum double salts were crystallized by a novel method involving a solid-liquid interface. The platinum complexes included Magnus Green Salt, MGS ([Pt(NH)3)4]2+ [PtCl4]2−) and PBC ([Pt(bpy)2]2+[Pt(CN)4]2−). The crystallization and molecular ordering of MGS and PBC on a Nafion membrane were achieved by controlling the diffusion of the cation and anion components to the solid-liquid interface. The electrical conductivity of the MGS film on Nafion was greatly augmented by oxidizing the polynuclear complex. A device consisting of the PBC film on Nafion, methyl viologen, and triethanolamine displayed photoelectrochromism.

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Authors and Affiliations

  1. Olin Hunt Speciality Products Inc., 02914, East Providence, Rhode Island, USA

    Kenji Honda

  2. Sagami Chemical Research Centre, 229, Sagamihara, Japan

    Kazuyuki Chiba

  3. Department of Polymer Chemistry, Waseda University, 160, Tokyo, Japan

    Eishun Tsuchida

  4. Solar Energy Research Institute, 80401, Golden, Colorado, USA

    Arthur J. Frank

Authors
  1. Kenji Honda
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  2. Kazuyuki Chiba
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  3. Eishun Tsuchida
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  4. Arthur J. Frank
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Honda, K., Chiba, K., Tsuchida, E. et al. Interfacial crystallization and electronic properties of platinum double salts. J Mater Sci 24, 4004–4008 (1989). https://doi.org/10.1007/BF01168965

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  • DOI: https://doi.org/10.1007/BF01168965

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