Skip to main content
Log in

Transparent monolithic zirconia gels: effects of acetylacetone content on gelation

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Transparent yttria-stabilized zirconia monolithic gels were synthesized under controlled conditions for hydrolysis and chemical polymerization. The influence of acetylacetone on the previous chemical reactions was explored, and a plausible explanation was proposed concerning the outstanding role of this additive during the gelation process. Small-angle X-ray scattering was used to estimate the size of the polymeric species and to investigate the influence of acetylacetone on the structure of the gels prepared.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. B. E. Yoldas,J. Mater. Sci. 12 (1977) 1203.

    Google Scholar 

  2. C. J. Brinker andG. W. Scherer,J. Non-Cryst. Solids 70 (1985) 301.

    Google Scholar 

  3. D. Ganguli andD. Kundu,J. Mater. Sci. Lett. 3 (1984) 503.

    Google Scholar 

  4. Idem, ibid. 5 (1986) 293.

    Google Scholar 

  5. K. S. Mazdiyasni, C. T. Lynch andJ. S. Smith,J. Amer. Ceram. Soc. 48 (7) (1965) 372.

    Google Scholar 

  6. B. Fegley Jr andE. A. Barringer, “Materials Research Society Symposia Proceedings”. Vol. 32, edited by C. J. Brinker, D. R. Ulrich and D. E. Clark (Elsevier North Holland, New York, 1984) p. 187.

    Google Scholar 

  7. P. Papet andJ. F. Baumard, presented at the Expermat'87, Bordeaux, France, edited by the CESTA, Paris, France (1987).

  8. A. Smith andJ. F. Baumard,Amer. Ceram. Soc. Bull. 66 (1987) 1144.

    Google Scholar 

  9. J. C. Debsikdar,J. Non-Cryst. Solids 86 (1986) 231.

    Google Scholar 

  10. J. C. Pouxviel, J. P. Boilot, A. Lecomte andA. Dauger,J. Physique 48 (1987) 921.

    Google Scholar 

  11. B. E. Yoldas,J. Non-Cryst. Solids 63 (1984) 145.

    Google Scholar 

  12. C. Sanchez, J. Livage, M. Henry andF. Babonneau,ibid. 100 (1988) 65.

    Google Scholar 

  13. A. Guinier andG. Fournet, “Small Angle Scattering of X-Rays” (Wiley, New York, 1955).

    Google Scholar 

  14. D. W. Schaefer andK. D. Keefer, “Better Ceramics Through Chemistry II”, Vol. 73, edited by C. J. Brinker, D. R. Ulrich and D. E. Clark (Elsevier, North-Holland, New York, 1986) p. 277.

    Google Scholar 

  15. B. B. Mandelbrot, “Fractals, Form and Chance” (Freeman, San Francisco, 1977).

    Google Scholar 

  16. D. W. Schaefer andK. D. Keefer, “Fractals in Physics” edited by L. Pietronew and E. Tossietti (Elsevier, Amsterdam, 1986) p. 39.

    Google Scholar 

  17. D. C. Bradley, R. C. Mehrotra andD. P. Gaur, in “Metal Alkoxides”, (Academic, London, 1978) p. 213.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Papet, P., Le Bars, N., Baumard, J.F. et al. Transparent monolithic zirconia gels: effects of acetylacetone content on gelation. J Mater Sci 24, 3850–3854 (1989). https://doi.org/10.1007/BF01168946

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01168946

Keywords

Navigation