Chemistry of Heterocyclic Compounds

, Volume 1, Issue 1, pp 27–29 | Cite as

Study of furan compounds. XXIX. Stereodirection of a reaction yielding 1, 6, 8-trioxaoispiro[]tridecene-12

  • A. A. Ponomarev
  • I. A. Markushina


Dielectric constants of solutions of 1, 6, 8-trioxadispiro[]tridecene-12 and 1, 6, 8-trioxadispiro[4.1. 4.2]tridecane are determined, and the dipole moments calculated.

Comparison of experimental and calculated dipole moments shows that electrolysis of a solution of 2, 5-furandipropanol-3 in methanol yields trans-1, 6, 8-trioxadispiro[]tridecene-12, thus indicating that the reaction of electrolytic alkoxylation of α, α′-furandialkanol-3s clearly differs from the stated stereodirection.


Methanol Organic Chemistry Dielectric Constant Dipole Moment Furan 
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Copyright information

© The Faraday Press, Inc. 1965

Authors and Affiliations

  • A. A. Ponomarev
    • 1
  • I. A. Markushina
    • 1
  1. 1.Chernyshevskii Saratov State UniversityUSSR

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