Abstract
Dielectric constants of solutions of 1, 6, 8-trioxadispiro[4.1.4.2]tridecene-12 and 1, 6, 8-trioxadispiro[4.1. 4.2]tridecane are determined, and the dipole moments calculated.
Comparison of experimental and calculated dipole moments shows that electrolysis of a solution of 2, 5-furandipropanol-3 in methanol yields trans-1, 6, 8-trioxadispiro[4.1.4.2]tridecene-12, thus indicating that the reaction of electrolytic alkoxylation of α, α′-furandialkanol-3s clearly differs from the stated stereodirection.
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Part XXVIII, see [1].
The authors thank O. A. Osipov and V. I. Minkin for facilities for making the measurements in the Chemistry Dept. Laboratory at Rostov University.
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Ponomarev, A.A., Markushina, I.A. Study of furan compounds. XXIX. Stereodirection of a reaction yielding 1, 6, 8-trioxaoispiro[4.1.4.2]tridecene-12. Chem Heterocycl Compd 1, 27–29 (1965). https://doi.org/10.1007/BF01168913
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DOI: https://doi.org/10.1007/BF01168913