Chemistry of Heterocyclic Compounds

, Volume 1, Issue 1, pp 19–22 | Cite as

Organosilicon compounds of the furan series. V. Furylorganylsilanes

  • E. Ya Lukevits
  • M. G. Voronkov


Twelve new furylorganylsilanes and furfurylorganylsilanes are synthesized by reacting 2-furyllithium, 5-methyl-2-furyllithium, and 5-trimethylsilyl-2-furyllithium with organylchlorosilanes, organylchlorohydrosilanes, chloromethyltriorganylsilanes, and silicon tetrachloride.

β-(2-furyl)ethyltrimethylsilane and 1-furyl-2-trimethylsilylethanol-1, which were previously unknown, are synthesized by reacting trimethylsilylmethyl magnesium chloride with furfuryl chloride and furfural, respectively.


Silicon Chloride Magnesium Organic Chemistry Furan 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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  1. 1.
    E. Lukevits, Izv. AN Latv. SSR, ser khim., p. 111, 1963.Google Scholar
  2. 2.
    R. Benkeser, R. Curie, J. Am. Chem. Soc., vol. 70, p. 1780, 1948.Google Scholar
  3. 3.
    C. Eaborn, J. A. Sperry, J. Chem. Soc., p. 4921, 1961.Google Scholar
  4. 4.
    R. Benkeser, H. Landesman, J. Am. Chem. Soc., vol. 71, p. 2493, 1949.Google Scholar
  5. 5.
    L. Sommer, R. Pioch, J. Am. Chem. Soc., vol. 76, p. 1606, 1954.Google Scholar
  6. 6.
    E. Lukevits, S. Giller, Izv. AN Latv. SSR, no. 4, p. 99, 1961.Google Scholar
  7. 7.
    H. Gilman, D. Miles, J. Org. Chem., vol. 23, p. 326, 1958.Google Scholar
  8. 8.
    E. Lukevits, S. Giller, Izv. AN Latv. SSR, no. 4, p. 95, 1961.Google Scholar
  9. 9.
    E. Lukevits, M. G. Voronkov, Izv. AN Latv. SSR, ser. khim., p. 127, 1961.Google Scholar
  10. 10.
    E. Lukevits, Yu. P. Romadan, S. A. Giller, M. G. Voronkov, DAN, vol. 145, p. 806, 1962.Google Scholar
  11. 11.
    A. D. Petrov, V. F. Mironov, V. A. Ponomarenko, E. A. Cherhyshev, Synthesis of Organosilicon Monomers [in Russian], Moscow, p. 424, 1961.Google Scholar
  12. 12.
    H. Gilman, J. Swiss, J. Am. Chem. Soc., vol. 62, p. 1847, 1940.Google Scholar

Copyright information

© The Faraday Press, Inc. 1965

Authors and Affiliations

  • E. Ya Lukevits
    • 1
  • M. G. Voronkov
    • 1
  1. 1.Institute of Organic Synthesis AS Latvian SSRRiga

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