Abstract
Twelve new furylorganylsilanes and furfurylorganylsilanes are synthesized by reacting 2-furyllithium, 5-methyl-2-furyllithium, and 5-trimethylsilyl-2-furyllithium with organylchlorosilanes, organylchlorohydrosilanes, chloromethyltriorganylsilanes, and silicon tetrachloride.
β-(2-furyl)ethyltrimethylsilane and 1-furyl-2-trimethylsilylethanol-1, which were previously unknown, are synthesized by reacting trimethylsilylmethyl magnesium chloride with furfuryl chloride and furfural, respectively.
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For Part IV see [1].
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Lukevits, E.Y., Voronkov, M.G. Organosilicon compounds of the furan series. V. Furylorganylsilanes. Chem Heterocycl Compd 1, 19–22 (1965). https://doi.org/10.1007/BF01168911
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DOI: https://doi.org/10.1007/BF01168911