Abstract
Furan undergoes a diene-synthesis type of reaction with acrylonitrile to give stereoisomeric 3, 6-endoxotetrahydrobenzonitriles whose configurations are established by PMR spectra. 2-Methylfuran undergoes a similar reaction with acrylonitrile. Some aspects of the relationship between the diene substitution reaction and substitutive addition in the furan series are considered.
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Communication XXXVIII, see [1].
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Yur'ev, Y.K., Zefirov, N.S., Ivanova, R.A. et al. Studies in the furan series. XXXIX. Reaction of furan and 2-methylfuran with acrylonitrile. Chem Heterocycl Compd 1, 1–4 (1965). https://doi.org/10.1007/BF01168907
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DOI: https://doi.org/10.1007/BF01168907