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Synthesis and reactions of oxygen-containing organosilicon compounds communication 1. Synthesis and some properties of trialkyl- and dialkylaryl-(2-chloroethoxy)silanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The reaction of ethylene oxide with the following trialkyl(or aryl)chlorosilances has been investigated: chlorotrimethyl-, chloroethyldimethyl-, chlorodiethylmethyl-, chlorotriethyl-, and chlorodiethylphyenyl-silances.

  2. 2.

    The following compounds have been prepared for the first time and characterized: (2-chloroethoxy)-triethyl-, and (2-chloroethoxy)diethylphenyl-silanes.

  3. 3.

    The proposed method is probably general for the preparation of various trialkyl(or arly) (2-haloethoxy) silanes from ethylene oxide and trialkyl(or aryl)chlorosilanes).

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Literature cited

  1. M. F. Shostakovsky, I. A. Shikhiev, and D. A. Kochkin, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1953, 5, 941 (T.p. 837).

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  2. M. F. Shostakovsky, K. A. Andrianov, I. A. Shikhiev, and D. A. Kochkin, Proc. Acad. Sci. USSR, 93, No. 4, 681 (1953).

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  3. M. F. Shostakovsky and D. A. Kochkin, Proc. Acad. Sci. USSR, 95, No. 4, 821 (1954)

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the USSR Academy of Sciences, USSR

    M. F. Shostakovsky, D. A. Kochkin & V. M. Vlasov

Authors
  1. M. F. Shostakovsky
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  2. D. A. Kochkin
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  3. V. M. Vlasov
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Shostakovsky, M.F., Kochkin, D.A. & Vlasov, V.M. Synthesis and reactions of oxygen-containing organosilicon compounds communication 1. Synthesis and some properties of trialkyl- and dialkylaryl-(2-chloroethoxy)silanes. Russ Chem Bull 3, 979–981 (1954). https://doi.org/10.1007/BF01168187

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  • DOI: https://doi.org/10.1007/BF01168187

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