Summary
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1.
The vinylation reactions of di- and tri-ethanolamines have been studied.
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2.
It has been shown that the vinylation of di- and tri-ethanolamines restuls in the synthesis of full and partial ethers, most of which have been prepared for the first time.
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3.
It has been shown that the vinyl ethers of diethanolamine, like that of 2-aminoethanol, do not undergo cyclization under the conditions of the synthesis.
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4.
A study has been made of some reactions of vinyl ethers of di- and tri-ethanolamines which prove their structures.
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5.
It has been found that the vinyl ethers of di- and tri-ethanolamines are less reactive in ion-catalyzed reactions than unsubstituted alkyl vinyl ethers.
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6.
It has been shown that the vinyl ethers of di- and tri-ethanolamines can polymerize in presence of 2,2'-azobis[2-methylpropionitrile].
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Shostakovsky, M.F., Chekulaeva, I.A. Synthesis and reactions of vinyl ethers of ethanolamines Communication 5. Vinyl ethers of di and tri-ethanolamines. Russ Chem Bull 3, 971–976 (1954). https://doi.org/10.1007/BF01168185
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DOI: https://doi.org/10.1007/BF01168185