Summary
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1.
By the decomposition of benzenediazonium fluoborate in a nitrile medium (benzonitrile, p- and o-tolunitriles, phenylacetonitrile, acetonitrile, propionitrile, and acrylonitrile), the corresponding anilides have been obtained in yields of up to 40%.
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2.
The occurrence of this reaction provides confirmation of the heterolytic character of the decomposition of benzenediazonium fluoborate.
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Makarova, L.G., Nesmeyanov, A.N. Decomposition and formation of onium salts and the synthesis of hetero-organic compounds Communication 8. Decomposition of benzenediazonium fluoborate in presence of nitriles. Russ Chem Bull 3, 887–891 (1954). https://doi.org/10.1007/BF01168172
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DOI: https://doi.org/10.1007/BF01168172