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Interhalogen compounds as complex-formers

  • General and Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Investigations on interhalogen compounds and the complex compounds that they form have made it possible to establish the structure of many such complex compounds, their chemical properties, and the nature of the ions that they form.

  2. 2.

    Double halides have been prepared in which iodine is present as a cation.

  3. 3.

    The field of complex compounds in which the central atom is a nonmetal has been extended.

  4. 4.

    It has been shown that complex compounds containing “acidocations” having a metalloid as central atom, are found more frequently than was previously thought.

  5. 5.

    Some generalizations have been made regarding the relation between the chemical properties and structures of complex compounds and the structures and polarizabilities of the original interhalogen molecules.

  6. 6.

    Some new ways have been found for the practical application of iodine halides (ICI and ICI3), for the quantitative determination of inorganic and organic substances, and for the preparation of iodine derivatives.

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Literature cited

  1. D. I. Mendeleev, Principles of Chemistry, 13th Edition, Moscow and Leningrad, 1947, p. 350.

  2. Beilst. 20, 189 (1935).

  3. Ya. A. Fialkov and I. D. Muzyka, J. Gen. Chem., 18, 1205 (1948).

    Google Scholar 

  4. H. Rheinbold, R. Roy, J. prakt. Chem. [2] 129, 273 (1931).

    Google Scholar 

  5. A. F. Scott, J. F. Bunnett, J. Am. Chem. Soc. 64, 2727 (1942).

    Google Scholar 

  6. E. Zappi, M. Fernandez, C. 1940, I. 1502.

  7. R. Cernatesen, M. Poni. Anal. Acad. Republ. populare Romane III, 1940 (1950).

  8. J. Cornog, H. Horrabin, R. Kages, J. Am. Chem. Soc., 60, 429 (1938).

    Google Scholar 

  9. Ya. A. Fialkov and K. I. Kaganskaya, J. Gen. Chem., 16, 1961 (1946); 18, 289 (1948).

    Google Scholar 

  10. E. Baudrimont, C. r. 55, 361 (1862).

    Google Scholar 

  11. Ya. A. Fialkov and A. A. Kuzmenko, J. Gen. Chem., 19, 812 (1949).(T.p. 797).

    Google Scholar 

  12. Ya. A. Fialkov and A. A. Kuzmenko, J. Gen. Chem., 19, 1007 (1949),(T.p. 997).

    Google Scholar 

  13. A. G. Sharpe, H. I. Emeleus, J. Chem. Soc. 1948, 2135.

  14. H. I. Emeleus, A. G. Sharpe, J. Chem. Soc. 1949, 2206.

  15. K. F. Luft Z. Phys. 84, 767 (1933).

    Google Scholar 

  16. F. Fairbrother, J. Chem. Soc. 1936, 847.

  17. Ya. A. Fialkov, Prog. Chem., 15, 485 (1946).

    Google Scholar 

  18. F. D. Shevchenko, Thesis, Kiev State Univ., 1951.

  19. L. Lilich, Thesis, “Spectrophotometric Investigation of Iodine Solutions”, Leningrad State Univ., 1949.

  20. S. A. Shchukarev and L. S. Lilich, Sci. Mem. Leningrad State Univ., Chemical Series No. 11. 3 (1952).

  21. S. A. Shchukarev, L. S. Lilich, and A. B. Sheinin, Proc. Acad. Sci., USSR, 85, 1333 (1952).

    Google Scholar 

  22. L. S. Lilich and O. E. Presnikova, Sci. Mem. Leningrad State Univ., Chemical Series No. 12, 3 (1953).

  23. I. A. Sheka, Bull. Platinum Sector of Inst. Gen. Inorg. Chem., Acad. Sci. USSR, 26, 189 (1951).

    Google Scholar 

  24. Ya. A. Fialkov and I. D. Muzyka, J. Gen. Chem., 18, 802 (1948).

    Google Scholar 

  25. Ya. A. Fialkov and I. D. Muzyka, J. Gen. Chem., 19, 416 (1949) (T.p. 1417); 20, 885 (1950) (T.p. 407).

    Google Scholar 

  26. Ya. A. Fialkov and I. D. Muzyka, J. Gen. Chem., 21, 823 (1951) (T.p. 905).

    Google Scholar 

  27. I. D. Muzyka, Ukr. Chem. J., 16, 331 (1950).

    Google Scholar 

  28. C. Sandonini, N. Berghello, Atti Reale Accad. del Lincei 25 (6) 46 (1937).

    Google Scholar 

  29. A. A. Woolf, H. J. Emeleus, J. Chem. Soc. 1949, 2865.

  30. N. N. Grinvud, Prog. Chem., 22, 445 (1953).

    Google Scholar 

  31. Ya. A. Fialkov and A. A. Kuzmenko, J. Gen. Chem., 19, 1645 (1949); 21, 473 (1951).

    Google Scholar 

  32. Ya. A. Fialkov, J. Gen. Chem., 11, 911 (1941).

    Google Scholar 

  33. Ya. A. Fialkov and O. I. Shor. J. Gen. Chem., 19, 1197, 1787; 23, 357,363 (1953).

  34. Ya. A. Fialkov and I. L. Abarbarchuk, Ukr. Chem. J., 15, 116, 126, 194, 372 (1949).

    Google Scholar 

  35. O. Ruff, Ber. 42, 4021 (1909).

    Google Scholar 

  36. O. Ruff, J. Zedner, L. Hecht, Ber. 48, 2068 (1915).

    Google Scholar 

  37. A. A. Grinberg, Introduction to the Chemistry of Complex Compounds, State Chem. Press, Leningrad and Moscow, 1951, p. 218.

    Google Scholar 

  38. V. Gutmann, Z. angew. Chem. 62, 312 (1950).

    Google Scholar 

  39. M. I. Usanovich, J. Gen. Chem., 9, 182 (1939); Bull. Acad. Sci. KazSSR, No. 5 (26), 22 (1947); No. 4, 97 (1951).

  40. M. I. Usanovich, The Nature of Acids and Bases, Acad. Sci. KazSSR Press, Alma-Ata, 1953.

    Google Scholar 

  41. A. I. Shatenshtein, Theories of Acids and Bases, State Chem Press, Moscow and Leningrad, 1949.

    Google Scholar 

  42. Ya. A. Filakov, A. A. Kuzmenko, and I. L. Abarbarchuk, Bull. Platinum Sector, 26, 124 (1951).

    Google Scholar 

  43. I. L. Abarbarchuk, Ukr. Chem. J., 19, 65 (1953).

    Google Scholar 

  44. V. Guttmann, H. Emeleus, J. Chem. Soc. 1950, 1046, 1950, 1046.

    Google Scholar 

  45. A. G. Sharpe, J. Chem. Soc. 1953, 197.

  46. A. I. Gengrinovich, Ukr. Pharm. J., 3, 15 (1940); 4, 23 (1940); Pharmacy, 6, 5 (1946).

    Google Scholar 

  47. A. I. Gengrinovich and Ts. I. Shakh. Medicinal Ind., 2, 3 (1948).

    Google Scholar 

  48. A. I. Gengrinovich and coworkers, Sci. Mem. Kiev Inst. Pharm. UkrSSR Medical Press, 1950, pp 58, 79, 87. 97, 104.

  49. A. I. Gengrinovich and M. S. Baron, Pharmacy News, No. 4, 1952, p. 27.

  50. Ts. I. Shakh, Medicinal Ind., 4, 29 (1951).

    Google Scholar 

  51. Ya. A. Fialkov and F. E. Kagan, Ukr. Chem. J., 18, 55, 64 (1952).

    Google Scholar 

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Authors and Affiliations

  1. Institute of General and Inorganic Chemistry of the Academy of Sciences of the UkrSSR, UkrSSR

    Ya. A. Fialkov

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  1. Ya. A. Fialkov
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Paper read at a Joint session of the Division of Physico-Mathematical, Chemical, and Geological Sciences of the Academy of Sciences of the Ukrainian SSR and the Division of Chemical Sciences of the Academy of Sciences of the USSR on May 11–13, 1954, In Lvov.

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Fialkov, Y.A. Interhalogen compounds as complex-formers. Russ Chem Bull 3, 847–855 (1954). https://doi.org/10.1007/BF01168166

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  • DOI: https://doi.org/10.1007/BF01168166

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