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X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 7. Thiocyanates and isothiocyanates

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

We propose an x-ray spectral criterion as a characteristic of organic and inorganic thiocyanates and isothiocyanates. We establish the lack of interaction between the level of the unshared electron pair of sulfur and the πc≡C-orbitals in thiocyanates.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistrym, Siberian Branch, Academy of Sciences of the USSR, USSR

    G. N. Dolenko, V. P. Elin, A. L. Litvin, O. Kh. Poleshchuk & E. V. Dolenko

Authors
  1. G. N. Dolenko
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  2. V. P. Elin
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  3. A. L. Litvin
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  4. O. Kh. Poleshchuk
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  5. E. V. Dolenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya, Khimicheskaya, No. 11, pp. 2519–2521, November, 1989.

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Dolenko, G.N., Elin, V.P., Litvin, A.L. et al. X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 7. Thiocyanates and isothiocyanates. Russ Chem Bull 38, 2311–2313 (1989). https://doi.org/10.1007/BF01168076

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  • DOI: https://doi.org/10.1007/BF01168076

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