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Thermodynamic characteristics of the radical cation of pyridine N-oxide and its reaction with methanol

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The thermodynamic characteristics of the pyridine N-oxide radical cation were obtained and the energetics of its hydration were estimated. The electrochemically generated pyridine N-oxide radical cations are capable of cleaving an H atom from methanol, which is a component of the medium.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    T. A. Echmaeva, S. I. Kulakovskaya, S. N. Shamaev & V. M. Berdnikov

Authors
  1. T. A. Echmaeva
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  2. S. I. Kulakovskaya
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  3. S. N. Shamaev
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  4. V. M. Berdnikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2438–2441, November, 1989.

We would like to express our deep appreciation to A. E. Shilov for his cooperation in the research and discussion of the results of the study.

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Echmaeva, T.A., Kulakovskaya, S.I., Shamaev, S.N. et al. Thermodynamic characteristics of the radical cation of pyridine N-oxide and its reaction with methanol. Russ Chem Bull 38, 2237–2240 (1989). https://doi.org/10.1007/BF01168059

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  • DOI: https://doi.org/10.1007/BF01168059

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