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Synthesis and properties of (1-methylallyl)- and 2-butenyl-silanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    It has been shown that in the Grignard-Wurtz synthesis of alkenylsilanes from 1-bromo-2-butenes, the latter undergo the same type of allyl rearrangement as in the synthesis of hydrocarbons, i.e., in the condensation of R- MgX

    are formed. When R-X is condensed with

    is formed.

  2. 2.

    Silicon analogs of olefins have been synthesized: (1-methylallyl)silane, 2-butenylsilane, methyl(1-methylallyl)silane, trichloro(1-methylallyl)silane, triethyl(1-methylallyl)silane, and trimethyl-3-pentenylsilane.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the USSR Academy of Sciences, USSR

    A. D. Petrov & V. A. Ponomarenko

Authors
  1. A. D. Petrov
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  2. V. A. Ponomarenko
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  3. V. I. Boikov
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Petrov, A.D., Ponomarenko, V.A. & Boikov, V.I. Synthesis and properties of (1-methylallyl)- and 2-butenyl-silanes. Russ Chem Bull 3, 429–434 (1954). https://doi.org/10.1007/BF01167821

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  • DOI: https://doi.org/10.1007/BF01167821

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