Summary
-
1.
A study has been made of the copolymerization of methyl methacrylate with alkyl vinyl ethers in presence of benzoyl peroxide at various monomer ratios.
-
2.
Copolymers of methyl methacrylate with alkyl vinyl ethers have been prepared.
-
3.
It has been shown that, in presence of benzoyl peroxide, copolymerization may be effected between alkyl vinyl ethers and compounds containing the system of double bonds:-C=C-C=O.
-
4.
In the copolymerization of methyl methacrylate with alkyl vinyl ethers in presence of benzoyl peroxide, no polymers of methyl methacrylate were detected.
Similar content being viewed by others
Literature cited
M. F. Shostakbvsky and A. M. Khomutov, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1953, No. 6, 1049.
M. F. Shostakovsky, I. A. Chekulaeva, and A. M. Khomutov, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1954, No. 2, 323.
M. F. Shostakovsky, Vinyl Ethers, Acad. Sci. USSR Press, Moscow, p. 219.
M. F. Shostakovsky, Investigations on Macromolecular Compounds, Acad. Sci. USSR Press, Moscow, 1949, p. 38.
I. P. Losev and E. B. Trostyanskaya, J. Gen. Chem., 17, 122 (1947).
V. V. Korshak, Chemistry of Macromolecular Compounds, Acad. Sci. USSR Press, Moscow, 1950, p. 240.
S. S. Medvedev, et. al., J. Phys. Chem., 17, 398 (1948).
Gelisen, Hetmans, Ber., 58, 285 (1925); 59, 63 (1926).
A. E. Favorsky and M. F. Shostakovsky, J. Gen. Chem., 13, 1 (1943).
F. Mayo, J. Am. Chem. Soc., 70, 4 (1948).
M. F. Shostakovsky, Investigations on Macromolecular Compounds, Acad. Sci. USSR Press, Moscow, 1949, p. 42.
S. N. Ushakov, S. P. Mintsingler, and G. A. Shtraikhman, Prog. Chem., 19, 1 (1950).
F. Lewis and others, J. Am. Chem. Soc., 70, 4, 1527 (1948).
F. Mayo, F. Lewis, W.Hulse, J. Am. Chem. Soc., 70, 4, 1523 (1948).
F. Lewis, F. Mayo, C. Walling, J. Am. Chem. Soc., 70, 1529 (1948).
V. V. Korshak, Chemistry of Macromolecular Compounds, Acad. Sci. USSR Press, 1950, p. 30.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Shostakovsky, M.F., Khomutov, A.M. Chemical reactions of unsaturated and macromolecular compounds Communication 2. Copolymerization of methyl methacrylate with alkyl vinyl ethers. Russ Chem Bull 3, 411–415 (1954). https://doi.org/10.1007/BF01167818
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01167818