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Reactions of cyclohexene at aluminosilicate catalysts of different alumina and silica contents under conditions precluding cracking. Selective poisoning by sodium ions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study has been made of the kinetics of the simultaneous reactions of polymerization, hydrogen redistribution, and isomerization under conditions precluding cracking, and it has been shown that the transformations of cyclohexene proceed at active centers of two types.

  2. 2.

    Hydrogen redistribution proceeds only at “acidic” aluminosilicate active centers. Isomerization proceeds at “acidic” active centers and on aluminum oxide.

  3. 3.

    Adsorption of sodium ions poisons aluminosilicate with respect to hydrogen redistribution and isomerization.

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Authors and Affiliations

  1. Petroleum Institute of the USSR Academy of Sciences, USSR

    K. V. Topchieva, A. P. Ballod, I. V. Patsevich & I. Ptishcheva

  2. M. V. Lomonosov Moscow State University, USSR

    K. V. Topchieva, A. P. Ballod, I. V. Patsevich & I. Ptishcheva

Authors
  1. K. V. Topchieva
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  2. A. P. Ballod
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  3. I. V. Patsevich
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  4. I. Ptishcheva
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Topchieva, K.V., Ballod, A.P., Patsevich, I.V. et al. Reactions of cyclohexene at aluminosilicate catalysts of different alumina and silica contents under conditions precluding cracking. Selective poisoning by sodium ions. Russ Chem Bull 3, 405–409 (1954). https://doi.org/10.1007/BF01167817

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  • DOI: https://doi.org/10.1007/BF01167817

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