Summary
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1.
Values of the group refractions of the two atoms of sulfur in esters and mixed anhydrides of phosphorothiolothionic acid have been determined. The values found for\(AR_{S_2 } \) are: for O,O-dialkyl S-hydrogen phosphorothiolothionates (RO)2PSSH 18.82: for trialkyl phosphorothiolothionates (RO)2PS(SR) 18.72; and for O,O-dialkyl S-acyl phosphorothiolothionates (RO)2PSSCOX 19.77.
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2.
The syntheses of S-acyl and S-alkoxycarbonyl derivatives of O,O-dialkyl S-hydrogen phosphorothiolothionates have been described.
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Kabachnik, M.I., Mastryukova, T. Atomic refraction of phosphorus and sulfur in phosphorothiolothionic esters. Russ Chem Bull 3, 369–373 (1954). https://doi.org/10.1007/BF01167812
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DOI: https://doi.org/10.1007/BF01167812