Summary
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1.
A study has been made of the decomposition, in an organic medium in presence of cuprous chloride, of the double salts formed by diazonium salts with antimony pentachloride; the reaction results in the formation of arylstibonic acids.
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2.
In a number of cases (phenyl-, p-tolyl-, p-nitrophenyl-, p-iodophenyl-, and 2-naphthyl-stibonic acids)
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3.
The nature of the by-products of the reaction indicates that the process is of a homolytic, not free-radical, character.
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Nesmeyanov, A.N., Reutov, O.A. & Knol, P.G. Synthesis of arylstibonic acids via double salts of diazonium salts and antimony pentachloride. Russ Chem Bull 3, 347–352 (1954). https://doi.org/10.1007/BF01167809
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DOI: https://doi.org/10.1007/BF01167809