Summary
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1.
The ethyl, isopropyl, isobutyl, and butyl 1,1-dimethyl-2-propynyl acetals of acetaldehyde have been prepared. The last has been described in the Wenture, but the first three are now synthesized for the first time.
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2.
The possibility of synthesizing the symmetrical acetylenic acetal
has been demonstrated for the first time.
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3.
The structures of the acetals obtained have been proved by hydrolytic breakdown into their components.
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4.
The disproportionation of unsymmetrical acetylenic acetals has been demonstrated for the first time.
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Shostakovsky, M.F., Shikhiev, I.A. Derivatives of tertiary unsaturated alcohols. Russ Chem Bull 2, 943–948 (1953). https://doi.org/10.1007/BF01167541
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DOI: https://doi.org/10.1007/BF01167541