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Isomerism of the dibromodinitroplatinate(II) ion

  • General and Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    It has been shown that, when equimolecular amounts of K2[PtBr4] and K2[Pt(NO2)4] react, the product has the composition K2[Pt(NO2)2Br2], and behaves like a mixture of geometric isomerides.

  2. 2.

    Treatment of a solution of the salt K2[Pt(NO2)2Br2], obtained as indicated above, with ammonia yields trans-dinitrodiammineplatinum:containing cis-dinitrodiammineplatinum impurity.

  3. 3.

    A new reaction has been applied for the distinguishing of the two isomers of dinitrodiammineplatinum.

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Literature Cited

  1. A. A. Grinberg, Introduction to the Chemistry of Complex Compounds, 1951.

  2. A. V. Babaeva, Proc. Acad. Sci. USSR, 81, 833 (1951).

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Authors and Affiliations

  1. V. G. Khlopin Radium Institute of the USSR Academy of Sciences, USSR

    A. A. Grinberg, A. I. Dobroborskaya & G. A. Shagisultanova

  2. Lensoviet Institute of Technology, USSR

    A. A. Grinberg, A. I. Dobroborskaya & G. A. Shagisultanova

Authors
  1. A. A. Grinberg
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  2. A. I. Dobroborskaya
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  3. G. A. Shagisultanova
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Grinberg, A.A., Dobroborskaya, A.I. & Shagisultanova, G.A. Isomerism of the dibromodinitroplatinate(II) ion. Russ Chem Bull 2, 861–864 (1953). https://doi.org/10.1007/BF01167527

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  • DOI: https://doi.org/10.1007/BF01167527

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