Summary
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1.
An investigation was made into the tendency of mono- and poly- alkenylsilanes to polymerize at ordinary and high pressures.
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2.
It was shown that the tendency of alkenylsilanes to polymerize varies with their structures.
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3.
It was shown that increase in pressure results in increase in the rate of polymerization of alkenylsilanes and in increase in the molecular weight of the resulting polymers.
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4.
An investigation was made into the copolymerization of methyl methacrylate with the following mono- and di-alkenylsilanes: allyldimethylphenyl-, diallyldimethyl-, diallylmethylphenyl-, and dimethylbis-2-methylallyl-silanes. Thermo-mechanical properties of the copolymers were determined.
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Polyakova, A.M., Korshak, V.V., Sakharova, A.A. et al. Polymerization and copolymerization of alkenylsilanes under high pressure Communication 3. Russ Chem Bull 5, 999–1005 (1956). https://doi.org/10.1007/BF01166416
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DOI: https://doi.org/10.1007/BF01166416