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Summary

  1. 1.

    By the action of acetyl, butyryl, and isobutyryl chlorides on some 1-hydroxyalkylphosphonic esters having a hydrogen on the 1-carbon, the corresponding acyl derivatives of the esters were obtained. Some of their physical constants were determined.

  2. 2.

    It was shown that similar compounds can be prepared by reaction of aldehydes with esters of mixed anhydrides of phosphorous acid and various carboxylic acids.

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Literature cited

  1. A. E. Arbuzov and P. I. Alimov, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1951, 409.

  2. V. S. Abramov, J. Gen. Chem. 22, No. 4, 647 (1952) (T.p. 709).

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  3. V. S. Abramov, L. P. Semenova and L. G. Semenova, Proc. Acad. Sci. USSR 84, No. 2, 281 (1952).

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Alimov, P.I., Cheplanova, I.V. Acyl derivatives of 1-hydroxyalkylphosphonic esters. Russ Chem Bull 5, 959–962 (1956). https://doi.org/10.1007/BF01166410

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  • DOI: https://doi.org/10.1007/BF01166410

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