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Derivatives of unsaturated phosphonic acids Communication 19. 2-chloro-3-butenyl- and 1,3-butyadienyl-phosphonic esters

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    With the aid of the addition reaction between phosphorus pentachloride and 1,3-butadiene, 2-chloro-3-butenylphosphonic dichloride was prepared.

  2. 2.

    The methyl, ethyl, propyl, isopropyl, butyl, isobutyl, allyl, hexyl, 2-methoxyethyl, and 2-ethoxyethyl esters of 2-chloro-3-butenylphosphonic acid were prepared by the action of alcohols on 2-chloro-3-butenylphosphonic dichloride, and some of their properties were determined.

  3. 3.

    By reaction between alcoholic potash and esters of 2-chloro-3-butenylphosphonic acid, the methyl, ethyl, propyl, isopropyl, butyl, isobutyl, allyl, hexyl, 2-methoxyethyl, and 2-ethoxyethyl esters of 1,3-butadienylphosphonic acid were synthesized.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR

    K. N. Anisimov & N. E. Kolobova

Authors
  1. K. N. Anisimov
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  2. N. E. Kolobova
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Anisimov, K.N., Kolobova, N.E. Derivatives of unsaturated phosphonic acids Communication 19. 2-chloro-3-butenyl- and 1,3-butyadienyl-phosphonic esters. Russ Chem Bull 5, 943–946 (1956). https://doi.org/10.1007/BF01166407

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  • DOI: https://doi.org/10.1007/BF01166407

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