Abstract
The methallyl moieties of [{(η3-C4H7)2Rh}2(V4O12)]2− couple to yield 2,5-dimethyl-1,5-hexadiene in a selective manner by the action of P(OEt),3, while the reaction of [(η 3-C4H7)2 Rh(acac)] with P(OEt)3 produces a mixture of organic compounds. The result shows that the vanadate support has a significant influence on the reactivity of organometallic complexes.
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References
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Abe, M., Akashi, H., Isobe, K. et al. Effects of a vanadate-support on the reactivity of theBis(Methallyl)Rhodium Complex [{(η3-C4H7)2Rh}2(V4O12)]2−. A comparison with the acetylacetonato complex. J Clust Sci 7, 103–107 (1996). https://doi.org/10.1007/BF01166179
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DOI: https://doi.org/10.1007/BF01166179