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5-[5-R-furfurylidene]-2,2-dimethyl-1,3-dioxane-4,6-diones 5. Nucleophilic replacement of halogen in the furan ring

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Halogen in positions 3 and 5 of the furan ring in ftirfurylidenedioxanediones is readily replaced by dithiocarbonate, dithiocarbatnate, dithiophosphate, thiocyanate, and azide anions, and by thiourea, and secondary and tertiary amines. The conformation of the initial halogen derivative is retained in the substitution products.

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Authors and Affiliations

  1. Kuban State Technological University, 350072, Krasnodar

    G. D. Krapivan, N. I. Val'ter, T. Ya. Kaklyugina & V. G. Kul'nevich

Authors
  1. G. D. Krapivan
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  2. N. I. Val'ter
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  3. T. Ya. Kaklyugina
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  4. V. G. Kul'nevich
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 327–334, March, 1994.

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Krapivan, G.D., Val'ter, N.I., Kaklyugina, T.Y. et al. 5-[5-R-furfurylidene]-2,2-dimethyl-1,3-dioxane-4,6-diones 5. Nucleophilic replacement of halogen in the furan ring. Chem Heterocycl Compd 30, 289–295 (1994). https://doi.org/10.1007/BF01165693

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  • DOI: https://doi.org/10.1007/BF01165693

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