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Researches in the field of phosphorus-organic compounds reaction of sulfides of phosphorus with alcohols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study has been made of the reactions of the sulfides of phosphorus P4S7, P4S6 and P4S8 wit alcohols.

  2. 2.

    Three types of products are obtained from P4S7 and ethanol, propanol or butanol, viz., (RO)2PSH, (RO)2PSSH, and (RO)2(RS)PS.

  3. 3.

    THe sulfide P4S7 and methanol give them esters (CH3O)2PSH and (CH3O)2(CH3S)PS.

  4. 4.

    The sulfide P4S6 reacts with alcohols to give esters of the types (RO)2PSH and (RO)2(RS)PS. Only with isopropabol does this sulfide give the esters (iso-C3H7O)2PSH and (iso-C3H7O)2PSSH.

  5. 5.

    The same products are obtained from the sulfide P4S5, or the 1:1 atomic sulfur-[hosphorus melt, and alcohols as with the sulfide P4S5, but the yields are lower.

  6. 6.

    The dialkyl dithiophosphates (RO)2PSSH have for the first time been prepared pure; they are liquids, which can be distilled in vacuum.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Academy of Sciences, USSR

    M. I. Kabachnik & T. A. Mastryukova

Authors
  1. M. I. Kabachnik
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  2. T. A. Mastryukova
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Kabachnik, M.I., Mastryukova, T.A. Researches in the field of phosphorus-organic compounds reaction of sulfides of phosphorus with alcohols. Russ Chem Bull 1, 661–666 (1952). https://doi.org/10.1007/BF01164935

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  • DOI: https://doi.org/10.1007/BF01164935

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