Abstract
We have investigated the molecular and crystal structure of 3, 7-di(2-propenyl)-1, 5-diphenyl-3, 7-diazabicyclo[3.3.1]nonan-9-one complexed with copper(II) chloride. We have shown for the first time that the reason for the distortion of the coordination polyhedron of the metal is the interaction of the substituents at the nitrogen atoms with the halogen atoms.
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Communication 2 in the series “Complexing properties of 3,7-diazabicyclo[3.3.1]nonanes.”
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 770–774, June, 1996. Original article submitted April 13, 1996.
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Vatsadze, S.Z., Sosonyuk, S.E., Zyk, N.V. et al. Molecular and crystal structure of 3,7-di(2-propenyl)-1,5-diphenyl-3,7-diazabicyclo[3.3.1]-nonan-9-one complexed with copper(II) chloride. Chem Heterocycl Compd 32, 661–665 (1996). https://doi.org/10.1007/BF01164864
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DOI: https://doi.org/10.1007/BF01164864