Skip to main content
SpringerLink
Log in

Dimeric covalently-bonded analogs of tetrabenzoporphyrin

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Thermal condensation of a mixture of N -potassium imnides of diphenylmethane-3, 3', 4, 4'-tetracarboxylic and phthalic acids in the presence of the acetates of sodium and zinc at 360-420°C gave the di-zinc complexes of methylene-bis-4, 4'-(tetrabenzoporphytin). This same scheme was used to prepare the di-zinc complex of methylene-bis-4, 4'[tri-2, 3-(I phenylnaphtho)]benzoporphine. Acidic treatment of the di-zinc complexes gave the free bases. The synthesized compounds were characterized by electronic, 1 H NMR, and IR spectra.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Hiom, J. B. Paine, and D. N. Dolphin, Can. J. Chem.,61, 2220 (1983).

    Google Scholar 

  2. G. V. Ponomarev and A. M. Shul'ga, Dokl. Akad. Nauk,271, 365 (1983).

    Google Scholar 

  3. B. Trost and K. Khatchitson (eds.), Organic Synthesis Today and Tomorrow [Russian translation], Mir, Moscow (1984).

    Google Scholar 

  4. A. F. Mironov, Vth Ail-Union Conf. on Coordination and Physical Chemistry of Porphyrins, Summary Report, Ivanovo (1988), p. 13.

  5. J. P. Colmann, F. G. Anson, C. S. Bencosme, C. E. Berries, T. Geiger, E. R. Evitt, R. P. Kreh, K. Meier, and H. B. Pettman, J. Am. Chem. Soc.,105, 2694 (1983).

    Google Scholar 

  6. C. C. Lenzoff, S. M. Marcuccio, S. Greenberg, A. B. P. Lever, and K. B. Tomer, Can. J. Chem.,63, 623 (1983).

    Google Scholar 

  7. V. N. Kopranenkov, A. M. Vorotnikov, T. M. Ivanova, and E. A. Luk'yanets, Khim. Geterotsikl. Soedin., No. 10, 1351 (1988).

  8. H. Stobbe, Chem. Ber.,40, 3372 (1907).

    Google Scholar 

  9. V. N. Kopranenkov, A. M. Voromikov, S. N. Dashkevich, and E. A. Luk'yanets, Zh. Org. Khim.,55, 900 (1985).

    Google Scholar 

  10. B. D. Berezin, E. B. Karavaeva, and T. 1. Potapova, Problems of Solvation and Complex Formation [in Russian], Ivanovo (1979), p. 25.

  11. K. H. Newmann, and F. Vögtle, J. Chem. Soc. Chem. Commun., 520 (1988).

  12. J. N. McCracken, J. G. D. Schulz, and A. S. Whitaker, US Patent 3,332,964, Ref. Zh. Khim., 2N186P (1969).

  13. Gulf Research and Development Co., US Patent 6,414,666, Chem. Abstr.,64, 6575 (1966).

Download references

Author information

Authors and Affiliations

  1. Scientific Research Institute of Organic Intermediates and Dyestuffs, 103787, Moscow

    A. M. Vorotnikov, V. N. Kopranenkov & E. A. Luk'yanets

Authors
  1. A. M. Vorotnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. N. Kopranenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. A. Luk'yanets
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 36–39, January, 1994.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vorotnikov, A.M., Kopranenkov, V.N. & Luk'yanets, E.A. Dimeric covalently-bonded analogs of tetrabenzoporphyrin. Chem Heterocycl Compd 30, 31–34 (1994). https://doi.org/10.1007/BF01164727

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01164727

Keywords

Search

Navigation