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Synthesis, nuclear magnetic resonance, and X-ray structural investigations of 1,6-diaza-9,12-dioxacyclotetradeca-2,5-dione

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Abstract

The molecular structure of l,6-diaza-9,12-dioxacyclotetradeca-2,5-dione has been investigated by X-ray and NMR methods. The crystals are monoclinic:C2/c,Z=4,a=8.5571(3),b=14.468(1),c=10.092(2) Å,β=113.38(1)°. The structure was solved by direct methods, and refined toR=0.051 on 1082 unique reflections. The molecule exhibits a crystallographic twofold symmetry axis, the axis bisecting the 3C-4C and 10C-11C bonds, which is in full agreement with NMR findings.

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References

  • Boeyens, J. C. A., and Dobson, S. M. (1987) InStereochemical and Stereophysical Behavior of Macrocycles, J. Bernal (ed.), (Elsevier, New York), pp. 1–102.

    Google Scholar 

  • Bradshaw, J. S., Krakowiak, K. E., and Zamecka-Krakowiak, D. J. (1989)Chem. Rev. 89, 929.

    Google Scholar 

  • Gluziński, P., Kasprzyk, S., Krajewski, J. W., Sałańiski, P., Stankiewicz, T., and Jurczak, J. (1991)J. Cryst. Spectr. Res. 21, 357.

    Google Scholar 

  • Jurczak, J., and Pietraszkiewicz, M. (1989) InHigh Pressure Chemical Synthesis, J. Jurczak and B. Baranowski, eds. (Elsevier, Amsterdam), pp. 294–321.

    Google Scholar 

  • Jurczak, J., Kasprzyk, S., Sałański, P., and Stankiewicz, T. (1991)J. Chem. Soc. Chem. Commun., 956.

  • Jurczak, J. (1986)Physica 139, 140B, 709.

    Google Scholar 

  • Sałański, P., Krajewski, J. W., Gluziński, P., Kasprzyk, S., Stankiewicz, T., and Jurczak, J. (1991)J. Cryst. Spectr. Res. 21, 195.

    Google Scholar 

  • Sheldrick, G. M. (1976)Shelx-76. Program for Crystal Structure Determination and Refinement (University of Cambridge, England). 400-Atomic Version (Ch. Weizman Institute of Science, Rehovot, Israel, 1979); implemented on IBM PC/AT (1987).

    Google Scholar 

  • Sheldrick, G. M. (1985)Crystallographic Computing 3. In G. M. Sheldrick, C. Krüger, and R. Goddard, eds. (Oxford University Press), pp. 175–189.

  • Sutherland, J. O. (1986)Chem. Soc. Rev. 15, 63.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Organic Chemistry, Polish Academy of Sciences, 01-224, Warszawa, Poland

    P. Gluziński, J. W. Krajewski, S. Kasprzyk, P. Sałański, T. Stankiewicz & J. Jurczak

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  1. P. Gluziński
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  2. J. W. Krajewski
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  3. S. Kasprzyk
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  4. P. Sałański
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  5. T. Stankiewicz
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  6. J. Jurczak
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Gluziński, P., Krajewski, J.W., Kasprzyk, S. et al. Synthesis, nuclear magnetic resonance, and X-ray structural investigations of 1,6-diaza-9,12-dioxacyclotetradeca-2,5-dione. Journal of Crystallographic and Spectroscopic Research 22, 15–19 (1992). https://doi.org/10.1007/BF01161357

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  • DOI: https://doi.org/10.1007/BF01161357

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