Skip to main content
SpringerLink
Log in

Crystal and molecular structure of 2,9-di-(methylnitronato)-3,5,10,12-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dienenickel(II) di-triethylammonium diperchlorate, C16H28N6O4Ni·2(C2H5)3NH·2ClO4

  • Published:
Journal of Crystallographic and Spectroscopic Research Aims and scope Submit manuscript

Abstract

The crystal and molecular structure of 2,9-di-(methylnitronato)-3,5,10,12-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dienenickel(II) di-triethylammonium diperchlorate (2c) has been determined of the basis of X-ray diffraction data. The crystals are monoclinic, space groupP21/c,Z=2; cell constantsα=11.478(3),b=15.177(3),c=11.431(3) Å,β=99.34(2)°. The structure was refined (full matrix, least squares) with 3408 unique reflections givingR=0.0616. An octahedral configuration of the Ni(II) coordination sphere was found to consist of the macrocycle N4 atoms occupying the equatorial plane of the octahedron with the O-atoms of the nitronato groups in the apical positions. The triethylammonium cations are hydrogen-bonded to the remaining O-atoms of the nitronato groups.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Boeyens, J. C. A., and Dobson, S. M. (1987) inStereochemistry of Organometallic and Inorganic Compounds, Bernal, I. (ed.), Vol. 2;Stereochemical and Stereophysical Behaviour of Macrocycles (Elsevier, Amsterdam, Holland), pp. 1–102.

    Google Scholar 

  • Korybut-Daszkiewicz, B. (1992)J. Chem. Soc. Dalton Trans. 7673–7679.

  • Krajewski, J. W., Gluziński, P., Korybut-Daszkiwicz, B., Ķemme, A., and Mishnyov, A. (1991)J. Chem. Soc. Dalton Trans. 53–56.

  • Sheldrick, G. M. (1976)SHELX-76. Program for crystal structure determination and refinement (University of Cambridge, England). 400-Atomic Version (Ch. Weizman Institute of Science, Rehovot, Israel, 1979); implemented on IBM PC/AT (1987).

    Google Scholar 

  • Sheldrick, G. M. (1985) in Sheldrick, G. M., Krüger, C., and Goddard, R. (eds.),Crystallographic computing 3. (Oxford University Press), pp. 175–189.

  • Walker, N., and Stuart, D. (1983)Acta Crystallogr. A 39, 158.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Chemistry, Polish Academy of Sciences, 01-224, Warszawa, Poland

    P. Gluziński, J. W. Krajewski & B. Korybut-Daszkiewicz

  2. Institute of Organic Synthesis, Latvian Academy of Sciences, 226006, Riga 6, Latvia

    A. Mishnyov & A. Ķemme

Authors
  1. P. Gluziński
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. W. Krajewski
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. Korybut-Daszkiewicz
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. Mishnyov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. Ķemme
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gluziński, P., Krajewski, J.W., Korybut-Daszkiewicz, B. et al. Crystal and molecular structure of 2,9-di-(methylnitronato)-3,5,10,12-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dienenickel(II) di-triethylammonium diperchlorate, C16H28N6O4Ni·2(C2H5)3NH·2ClO4 . Journal of Crystallographic and Spectroscopic Research 23, 61–64 (1993). https://doi.org/10.1007/BF01161289

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01161289

Keywords

Search

Navigation