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Crystal structure of trinuclear trans-μ3-oxo-tris{bischloroacetatoaquochromium(III)}chloroacetate dihydrate, [Cr3O(ClCH2COO)63H2O]ClCH2COO·2H2O

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Abstract

The structure of trans-μ 3-oxotris{bischloroacetatoaquochromium(III)}chloroacetate dihydrate consists of three octahedrally coordinated chromium atoms in the same plane linked axially to an oxygen atom in the center. The other axial positions are coordinated to water molecules. The anions and water of crystallization are involved in forming a three-dimensional hydrogen bonding array. Crystals of [Cr3O(ClCH2COO)63H2O)]+ ClCH2COO−·2H2O,M r =916.53, are prismatic in theP21/n space group witha=10.909(4),b=14.153(4),c=22.082(9) Å,β=102.67(3)°,V=3326(4) Å3, andZ=4.

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Authors and Affiliations

  1. Department of Chemistry, University of Malaya, 59100, Kuala Lumpur, Malaysia

    Meng -Chay Lim, Wei Chen, Seng -Neon Gan & Aishah Mohd Jelan

  2. Department of Chemistry, Howard University, 20059, Washington, D.C.

    Ray J. Butcher

Authors
  1. Meng -Chay Lim
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  2. Wei Chen
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  3. Seng -Neon Gan
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  4. Aishah Mohd Jelan
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  5. Ray J. Butcher
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Lim, M.C., Chen, W., Gan, S.N. et al. Crystal structure of trinuclear trans-μ3-oxo-tris{bischloroacetatoaquochromium(III)}chloroacetate dihydrate, [Cr3O(ClCH2COO)63H2O]ClCH2COO·2H2O. Journal of Crystallographic and Spectroscopic Research 23, 13–18 (1993). https://doi.org/10.1007/BF01161281

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  • DOI: https://doi.org/10.1007/BF01161281

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