Abstract
3-(2-(1,10-Phenanthrolyl))-5,6-diphenyl-1,2,4-triazine-chloroaquotriphenyl-tin(IV) (1:1) crystallizes in the orthorhombic system:a=19.195,b=9.144,c=21.642 Å,Z=4, space groupPca21 (No. 29). The structure was determined using the procedure for difference structures (Dirdir) with CuKα diffractometer data, and refined by block-diagonal least squares toR=0.031 for 3287 observed reflections. The tin atom is 5-coordinate with the three phenyl groups forming the equatorial plane. A chlorine atom and a water molecule complete the coordination. The triazine moiety does not coordinate directly to the metal atom. The only interaction is due to two N ⋯ H-O hydrogen bonds formed between two nitrogen atoms from the ligand and the water molecule.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Beurskens, P. T., and Van den Hark, Th. E. M. (1980) inTheory and Practice of Direct Methods in Crystallography, M. F. C. Ladd and R. A. Palmer, eds. (Plenum Press, New York), p. 255 and references therein.
Case, F. H. (1965)J. Org. Chem. 30, 931.
Domingos, A. M., and Sheldrick, G. M. (1974)J. Organomet. Chem. 67, 257.
Donnay, G., Donnay, J. D. H., and Harding, M. J. C. (1965)Acta Crystallogr. 19, 688.
Einstein, F. W. B., and Penfold, B. R. (1968)J. Chem. Soc. A, 3019.
Ferguson, J. E., Roper, W. R., and Wilkins, C. J. (1965)J. Chem. Soc. A, 3716.
Hamilton, W. C. (1965)Acta Crystallogr. 18, 502.
Harrison, P. G., King, T. J., and Richards, J. A. (1974)J. Chem. Soc. Dalton Trans. 1723.
Harrison, P. G., Molloy, K., Phillips, R. C., Smith, P. J., and Crowe, A. J. (1978)J. Organomet. Chem. 160, 421.
Hoppe, W. (1965)Angew. Chem. 77, 484.
International Tables for X-Ray Crystallography (1974) Vol. IV, J. A. Ibers and W. C. Hamilton, eds., (Kynoch Press, Birmingham).
Main, P., Fiske, S. J., Hull, S. E., Lessinger, L., Germain, G., Declercq, J.-P. and Woolfson, M. M. (1980)Multan 80: A System of Computer Programs for the Automatic Solution of Crystal Structures from X-Ray Diffraction Data. University of York, England, and Louvain, Belgium.
May, J. C. and Curran, C., (1972)J. Organomet. Chem. 39, 289.
Naik, D. V., and Scheidt, W. R. (1973)Inorg. Chem. 12, 272.
Pelizzi, C., and Pelizzi, G. (1976)Inorg. Chim. Acta. 18, 139.
Smith, F. E., and Liengme, B. V. (1975)J. Organomet. Chem. 91, C31.
Stewart, J. M., Kruger, G. J., Ammon, H. L., Dickinson, C. H., and Hall, S. R. (1972) TheX-ray System-Version of June 1972. Tech. Rep. TR-192. Computer Science Center, University of Maryland, College Park, Maryland.
Sutton, L. E., ed. (1958)Tables of Interatomic Distances and Configuration in Molecules and Ions (The Chemical Society, London).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ladd, M.F.C., Povey, D.C. & Smith, F.E. Crystal and molecular structure of 3-(2-(1,10-phenanthrolyl))-5,6-diphenyl-1,2,4-triazine-chloroaquotriphenyltin(IV) (1:1). Journal of Crystallographic and Spectroscopic Research 14, 249–259 (1984). https://doi.org/10.1007/BF01161162
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01161162