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Structure and IR spectroscopic properties ofN-methylmorpholinium pentachlorophenolate-pentachlorophenol

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Abstract

The crystal structure of C5H11OND+C6Cl5O−·C6Cl5OD has been determined by X-ray diffraction. The crystals are triclinic:P¯1,a=9.443(7),b=7.534(6),c=18.05(2) Å,α=91.23(7),β=95.83(6), γ=110.67(6)°,Z=2. The structure was solved by direct methods, and refined toR=0.033 for 2779 non-zero reflections. The structure consists of theN-methylmorpholinium cations and deuterium bis(pentachlorophenolate) homoconjugated anions. The N+-D(1)⋯O(l)− and O(2)-D(2)⋯O(1)− bond lengths and angles are 2.654(4), 2.557(4) Å, and 171(4), 158(5)°, respectively.

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References

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Authors and Affiliations

  1. Institute of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383, Wrocław, Poland

    I. Majerz, Z. Malarski & T. Lis

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  1. I. Majerz
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  2. Z. Malarski
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  3. T. Lis
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Majerz, I., Malarski, Z. & Lis, T. Structure and IR spectroscopic properties ofN-methylmorpholinium pentachlorophenolate-pentachlorophenol. Journal of Crystallographic and Spectroscopic Research 20, 187–192 (1990). https://doi.org/10.1007/BF01160973

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  • DOI: https://doi.org/10.1007/BF01160973

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