Abstract
The title compound crystallizes in the orthorhombic space groupPna21, witha=15.576(2),b=19.134(3),c=5.693(1) Å andz=4. The structure was solved by direct methods, and refined to a finalR value of 0.059. This study confirms both the structure and stereochemistry of the title compound.
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References
Conia, J. M., and Salaun, J. R. (1964)Bull Soc. Chem. Fr. 1957.
Conia, J. M., and Ripoll, J. L. (1963)Bull Soc. Chem. Fr. 773.
Conia, J. M., and Salaun, J. R. (1972)Acc. Chem. Res. 5 33.
Johnson, C. K. (1976)Ortep II. Report ORNL-5138. (Oak Ridge National Laboratory, Tenn.).
Kennard, O., and Watson, D. G. (1972)Molecular Structures and Dimensions (Oesthoek, Utrecht, A1, 2).
Kremer, P. W. (1976) Ph.D., Thesis, Marquette University Milwaukee.
Main, P. K., Lessinger, L., and Woolfson, M. M. (1978)Multan, A system of Computer Program for the Automatic Solution of Crystal Structures from X-ray Diffraction Data (University of York).
Mazhar-Ul-Haque, (1970)J. Chem. Soc. B, 938.
Mazhar-Ul-Haque, (1971)J. Chem. Soc. B, 117.
Mazhar-Ul-Haque, Rashid, M., and Cremer, S. E. (1978)J. Chem. Soc. Perkin Trans. 2, 1115.
Mazhar-Ul-Haque, Horne, W., Cremer, S. E., Kremer, P. W. and Most, T. J. (1980)J. Chem. Soc. Perkin Trans. 2, 1467.
Mazhar-Ul-Haque, Horne, W., Cremer, S. E. and Most, T. J. (1981)J. Chem. Soc. Perkin Trans. 2, 1000.
Mazhar-Ul-Haque, Horne, W., Cremer, S. E., Kremer, P. W., and Kafaraski, P. K. (1981)J. Chem. Soc. Perkin Trans. 2, 1138.
Mazhar-Ul-Haque, Ahmed, J., and Horne, W. (1983)Acta Crystallgr. C 39, 383.
Shefter, E., and Trueblood, K. N. (1965)Acta Crystallogr. 18, 1067.
Sheldrick, G. M. (1976)Shelx76, Program for Crystal Structure Determination (University of Cambridge, England).
Swank, D. D., Caughlan, C. N., Rameriz, F., Madan, O. P., and Smith, P. (1969)J. Am. Chem. Soc. 89, 6503.
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Mazhar-Ul-Haque, Ahmed, J., Horne, W. et al. Crystal and molecular structure of phenylbenzyl-1-(2,2,3-trimethylcyclopropyl)phosphine oxide. Journal of Crystallographic and Spectroscopic Research 19, 1009–1016 (1989). https://doi.org/10.1007/BF01160883
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DOI: https://doi.org/10.1007/BF01160883