Skip to main content
SpringerLink
Log in

Di-μ-sulphido-bis[4-methyl-piperidinedithiocarbamate tin(IV)]: Synthesis, characterization, and crystal and molecular structure

  • Published:
Journal of Crystallographic and Spectroscopic Research Aims and scope Submit manuscript

Abstract

The title compound, C15H26SnN2S5Cl2, was prepared, and characterized by means of X-ray and IR measurements. The crystals are monoclinic, space groupP21/n, (non standard setting ofP21/c, No. 14) witha=12.330(2),b=11.930(1),c=17.055(2) Å,β=106.21(1)° andZ=4.

The structure was solved by the heavy-atom method, and least-squares refinement of the structural parameters led to a conventionalR factor of 0.028 for 1284 independent reflections. The structure consists of discrete dimeric units with the metal coordinated to six sulphur atoms. The IR spectrum is consistent with the presence of the sulphur bridge atoms between the two metal ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Benedetti, A., Fabretti, A. C., and Preti, C. (1989)J. Cryst. Mol. Struct. 18, 685–692.

    Google Scholar 

  • Bonati, F., Minghetti, G., and Cenini, S. (1968)Inorg. Chim. Acta 2, 375–378.

    Google Scholar 

  • Bonati, F., and Ugo, R. (1967)J. Organomet. Chem. 10, 257–268.

    Google Scholar 

  • Bradley, D. C., and Gitlitz, M. H. (1969)J. Chem. Soc. A, 1152–1156.

  • Coulson, C. A. (1939)Proc. Roy. Soc. A,169, 413.

    Google Scholar 

  • Desseyn, H. O., Fabretti, A. C., Forghieri, F., and Preti, C. (1985)Spectrochim. Acta A 41, 1105–1108 (and refs. therein).

    Google Scholar 

  • Gable, R. W., Raston, C. L., Rowbottom, G. L., White, A. H., and Winter, G. (1981)J. Chem. Soc. Dalton Trans. 1392–1397.

  • Harreld, C. S., and Schlemper, E. O. (1971)Acta Crystallogr. B 27, 1964–1969.

    Google Scholar 

  • International Tables for X-Ray Crystallography (1974) (Kynoch Press, Birmingham, England), p. 177.

  • Johnson, C. K. (1965)Ortep, ReportOrnl-3794 (Oak Ridge National Laboratory, Oak Ridge, Tenn.). therein.

    Google Scholar 

  • Liquori, A. M., and Vaciago, A. (1956)Gazz. Chim. Ital. 86, 769.

    Google Scholar 

  • North, A. C. T., Phillips, D. C., and Mathews, F. S. (1968)Acta Crystallogr. A 24, 351–359.

    Google Scholar 

  • Pauling, L. (1960)The Nature of the Chemical Bond, (third edition) (Cornell University Press, Ithaca, NY).

    Google Scholar 

  • Perry, D., and Geanangel, R. A. (1975)Inorg. Chim. Acta 13, 185–189.

    Google Scholar 

  • Potenza, J., Johnson, R. J., and Mastropaolo, D. (1976)Acta Crystallogr. B 32, 941–943.

    Google Scholar 

  • Sheldrick, G. M. (1976)Shelx76, program for crystal structure determination (University Chemical Laboratory, Cambridge, England).

    Google Scholar 

  • Zubieta, I. A., and Zuckerman, J. J. (1978)Prog. Inorg. Chem. 24, 251–425.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dipartimento di Chimica, University of Modena, Via G. Campi, 183, 41100, Modena, Italy

    Antonio C. Fabretti & Carlo Preti

Authors
  1. Antonio C. Fabretti
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Carlo Preti
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fabretti, A.C., Preti, C. Di-μ-sulphido-bis[4-methyl-piperidinedithiocarbamate tin(IV)]: Synthesis, characterization, and crystal and molecular structure. Journal of Crystallographic and Spectroscopic Research 19, 957–966 (1989). https://doi.org/10.1007/BF01160878

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01160878

Keywords

Search

Navigation