Abstract
The 1∶1 methylmercury complex withl-alanine belongs to the orthorhombic space groupP212121. The unit cell of dimensionsa=5.763(3),b=6.851(6),c=18.75(2) Å contains four molecules. The structure was refined on 584 nonzero reflections toR=0.050. The methylmercury ion has replaced an ammonium proton and is linearly bonded to the nitrogen atom. Mercury is also involved in secondary inter- and intramolecular contacts with carboxylate oxygen atoms. Infrared and Raman spectra of the amino-deuterated complex are discussed and compared with those of the undeuterated compound. A correlation is found between backbone conformation and the pattern ofυ Hg-N andυ Hg-C bands in the Raman spectra.
Similar content being viewed by others
References
Alcock, N. W., Lampe, P. A., and Moore, P. (1978)J. Chem. Soc. Dalton Trans. 1324.
Alex, S., Savoie, R., Corbeil, M. C., and Beauchamp, A. L. (1986)Can. J. Chem. 64, 148.
Authier-Martin, M., and Beauchamp, A. L. (1977)Can. J. Chem. 55, 1213.
Charland, J. P., and Beauchamp, A. L. (1985)J. Crystallogr. Spectrosc. Res. 15, 581.
Corbeil, M. C., and Beauchamp, A. L. (1988a)Can. J. Chem. 66, 1379.
Corbeil, M. C., and Beauchamp, A. L. (1988b)Can. J. Chem. 66, 2458.
Corbeil, M. C., Beauchamp, A. L., Alex, S., and Savoie, R. (1986)Can. J. Chem. 64, 1876.
Cromer, D. T., and Mann, J. B. (1968)Acta Crystallogr. A24, 321.
Cromer, D. T. (1965)Acta Crystallogr. 18, 17.
Dupuy, B., Castinel, C., and Garrigou-Lagrange, C. (1969)Spectrochim. Acta 25A, 571.
Jackovitz, J. F., Durkin, J. A., and Walter, J. L. (1967)Spectrochim. Acta 23A, 67.
Lehmann, M. S., Koetzle, T. F., and Hamilton, W. C. (1972)J. Am. Chem. Soc. 94, 2657.
Stewart, R. F., Davidson, E. R., and Simpson, W. T. (1965),J. Chem. Phys. 42, 3175.
Stout, G. H., and Jensen, L. H. (1968) X-Ray Structure Determination, a Practical Guide. (Macmillan, London).
Wong, Y. S., Carty, A. J., and Chieh, P. C. (1977a)J. Chem. Soc. Dalton Trans. 1157.
Wong, Y. S., Carty, A. J., and Chieh, P. C. (1977b)J. Chem. Soc. Dalton Trans. 1801.
Wong, Y. S., Chieh, P. C., and Carty, A. J. (1973)Can. J. Chem. 51, 2597.
Wong, Y. S., Taylor, N. J., Chieh, P. C., and Carty, A. J. (1974)J. Chem. Soc. Chem. Commun. 625.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Corbeil, MC., Beauchamp, A.L. Crystal structure and vibrational spectra of the methylmercury complex withl-alanine. Journal of Crystallographic and Spectroscopic Research 19, 123–134 (1989). https://doi.org/10.1007/BF01160849
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01160849