Abstract
Mw=403,2 amu,P21/c,a 18.944(8) Å,b=8.540(4) Å,c=10.794(7) Å,β=98.11(4)°,V=1729(2) Å3,Z=4,D x=1.548 g·cm−3,μ (MoKα)=4.26 cm−1; m.p. 202–204°C. FinalR=0.083 for 1632 independent observed reflections having 2θ (Mo Kά)<50° andI>2 σ(I). The molecule has an extended overall nonplanar conformation with onecis and twotrans-C(O)-NH- units and intramolecular hydrogen bridges. The relatively highR factor is on account of conformational disorder of the trifluoromethyl and chloro substituents of the 2-chloro-3,3,3-trifluoropropenyl moiety.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Bart, J. C. J., Scordamaglia, R., and Calcaterra, M. (1985)J. Crystallogr. Spectr. Res. 15, 61.
Brown, C. J. (1966).Acta Cryst. 21, 442–445.
Churchill, M. R. (1973).Inorg. Chem. 12, 1213–1214.
Cromer, D. T., and Mann, J. B. (1968)Acta Cryst. A24, 321–324.
Cruickshank, D. W. J. (1965).Computing Methods in Crystallography, edited by Rollett J. S., (Pergamon Press, Oxford) ch. 14.
Dewar, M. J. S., and Schmeising, H. N. (1968)Tetrahedron 11, 96–120.
Domenicano, A., Mazzeo, P., and Vaciago, A. (1976)Tetrah. Lett. 1029–1032.
Dudek, G. O., and Holm, R. H. (1962)J. Am. Chem. Soc. 84, 2691–2696.
Dudek, G. O., and Volpp, G. P. (1963)J. Am. Chem. Soc. 85, 2697–2702.
Fletterick, R. J., Tsai, C., and Hughes, R. E. (1971)J. Phys. Chem. 75, 918–922.
Lofthus, A. (1959).Mol. Phys. 2, 367–371.
Main, P., Lessinger, L., Woolfson, M. M., Germain, G., and Declercq, J. P. (1978)MULTAN78: A System of Computer Programs for the Automatic Solution of Crystal Structures from X-ray Diffraction Data (Univ. of York, U. K., and Louvain, Belgium).
Massardo, P., Bettarini, F., Giovarruscio, G., Piccardi, P., Reggiori, F., Caprioli, V., and Longoni, A. (1983)Ital. Pat. Appl. 20.744 A/83.
Motherwell, S. (1979)PLUTO, A Program for Plotting Molecular and Crystal Structures (University of Cambridge).
Pauling, L. (1960)The Nature of the Chemical Bond, third edition (Cornell University Press, Ithaca, N. Y.), p. 260.
Philips Gloeilampenfabrieken, Neth. Pat. Appl. 7.105.350 (April 21, 1971).
Stewart, W. E., and Siddall, T. H. (1970)Chem. Rev. 70, 517–551.
Sutton, L. E. (1965)Tables of Interatomic Distances and Configuration in Molecules and Ions, Spec. Publ. No. 18, The Chemical Society, London.
Wellinga, K., and Mulder, R. (to U.S. Philips Co.), U.S. Pat. 3,989,842 (Nov. 2, 1976).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bart, J.C.J., Calcaterra, M., Cavigiolo, W. et al. Structure of the larvicideN-(2-chlorobenzoyl)-N′-[4-(2-chloro-3,3,3-trifluoroprop-1-enyl)phenyl]urea, C17H11Cl2F3O2N2 . Journal of Crystallographic and Spectroscopic Research 19, 99–108 (1989). https://doi.org/10.1007/BF01160847
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01160847