Skip to main content
Log in

Preparation and properties of nickel silicide layers by the diffusion and CVD processes using Si2Cl6 as a source of silicon

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Nickel plate was siliconized with a gas mixture of Si2Cl6, H2 and argon in the temperature range 400 to 900° C, and the siliconizing conditions and some of its properties were examined, Appreciable weight increase of the nickel plate was observed above 450° C, which is 200 to 300° C lower than that obtained using SiCl4 as a source of silicon. Siliconizing of the surface and the resistance to high-temperature oxidation and hot corrosion were improved, Nickel silicide layers were also obtained by the CVD process using a gas mixture of Si2Cl6, H2 and argon.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. B. Fraser, E. Kinsbron andF. Vratny, US Patent 4 362 597 (1983).

  2. R. Gonsiorawski andK. B. Patel, UK Patent Application, GB 2107 741 (1983) (Chem. Abstr.99 (1983) 9528e).

  3. M. Houalla, C. L. Kibby, L. Petrakis andD. M. Hercules,J. Phys. Chem.87 (1983) 3689.

    Article  CAS  Google Scholar 

  4. H. Imamura andW. E. Wallace,ibid.83 (1979) 2009.

    Article  CAS  Google Scholar 

  5. A. M. Leas, US Patent 4 167 615 (1979).

  6. E. D. Dickens Jr, US Patents 3 968 064 (1976), 3 975 359 (1976).

  7. E. Fitzer, H. J. Maeurer, W. Nowak andJ. Schlichting,Thin Solid Films64 (1979) 305.

    Article  CAS  ADS  Google Scholar 

  8. A. M. Beltran, N. R. Lindblad andG. E. Wasielewski, US Patent 3 904 328 (1976).

  9. A. A. Appen, N. S. Andrushchenko, I. B. Baivkovskaya andM. V. Sazonova,Fiz. Khim. Obrab. Mater.6 (1972) 51 (Chem. Abstr.78 (1973) 86625c).

    Google Scholar 

  10. K. N. Tu, E. I. Alessaudrini, W. K. Chu, H. Kroütle andJ. W. Mayer,Jpn. J. Appl. Phys.13 Suppl. 2, Part 1 (1974) 669.

    Google Scholar 

  11. T. G. Finstad, J. W. Mayer andM-A. Nicolet,Thin Solid Films51 (1978) 391.

    Article  CAS  ADS  Google Scholar 

  12. R. Pretorius, C. L. Ramitter, S. S. Lau andM-A. Nicolet,Appl. Phys. Lett.30 (1977) 501.

    Article  CAS  ADS  Google Scholar 

  13. J. E. E. Baylin, H. A. Atwater, D. Gupta andF. M. D'Heurle,Thin Solid Films93 (1982) 255.

    Article  ADS  Google Scholar 

  14. A. I. Rodionov andV. A. Uskov,Izv. Vyssh. Uchebn. Zaved. Fiz.28 (1985) 78 (Chem. Abstr.102 (1985) 226315t).

    CAS  Google Scholar 

  15. B. L. Meiler,Poverkhnost4 (1985) 67 (Chem. Abstr.102 (1985) 195982b).

    Google Scholar 

  16. L. J. Chen, L. S. Hung, J. W. Mayer, J. E. E. Baglin, J. M. Nerz andD. A. Hammer,Appl. Phys. Lett,40 (1982) 595.

    Article  CAS  ADS  Google Scholar 

  17. A. J. Gay andJ. Qaukernaat,J. Less-Common Metals40 (1975) 21.

    Article  CAS  Google Scholar 

  18. K. Hikosaka, H. Ishiwara andS. Furukawa,J. Vac. Sci. Technol.16 (1979) 1913.

    Article  CAS  ADS  Google Scholar 

  19. V. Yu. Petukhov, I. B. Khaibullin andM. M. Zaripov,Poverkhnost2 (1985) 104.

    Google Scholar 

  20. E. Fitzer, H. J. Maeurer, W. Nowak andJ. Schlichting,Thin Solid Films64 (1979) 305.

    Article  CAS  ADS  Google Scholar 

  21. M. Sokolowski, A. Sololowska, E. Rolinski andA. Michalski,ibid.30 (1975) 29.

    Article  CAS  ADS  Google Scholar 

  22. D. Itzhak, F. R. Tuler andM. Schieber,ibid.73 (1980) 379.

    Article  CAS  ADS  Google Scholar 

  23. A. Olsen andF. R. Sale,Met. Technol.7 (1980) 494 (Chem. Abstr.94 (1981) 196446h).

    CAS  Google Scholar 

  24. K. N. Tu, G. Ottaviani, U. Gosele andH. Foll,J. Appl. Phys.54 (1983) 758.

    Article  CAS  ADS  Google Scholar 

  25. M. Bartur andM-A. Nicolet,ibid.54 (1983) 5404.

    Article  CAS  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Motojima, S., Kohno, M. & Hattori, T. Preparation and properties of nickel silicide layers by the diffusion and CVD processes using Si2Cl6 as a source of silicon. J Mater Sci 22, 547–553 (1987). https://doi.org/10.1007/BF01160767

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01160767

Keywords

Navigation