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Studies of systemic acylanilide fungicides. Part II. Crystal structure and molecular conformation ofdl-methylN-(2,6-dimethylphenyl)-N-(2-furoyl)alaninate

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Abstract

A crystalline modification of the title compound (C17H19NO4) was determined by three-dimensional X-ray analysis from diffractometer data. Crystal data: monoclinic,Cc,a=15.997(12) Å,b=7.929(7) Å,c=14.664(11) Å,β=118.70(5)°,Z=4;Dx=1.227 Mg m−3,μ(MoKα)=0.094 mm−1. FinalR=0.068 for 852 observed reflections. The dimethylphenyl ring is strongly twisted (94.9°) with respect to the amidic plane of the molecule, which almost coincides with the furan ring (6.9°).

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Author notes

  1. J. C. J. Bart

    Present address: I.R.C.-C.N.R.S., 2 av. Albert Einstein, 69626, Villeurbrane Cedex, France

Authors and Affiliations

  1. Istituto G. Donegani S.p.A. (Montedison), Via G. Famer 4, 28100, Novara, Italy

    J. C. J. Bart, R. Scordamaglia & M. Calcaterra

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  2. R. Scordamaglia
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  3. M. Calcaterra
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Bart, J.C.J., Scordamaglia, R. & Calcaterra, M. Studies of systemic acylanilide fungicides. Part II. Crystal structure and molecular conformation ofdl-methylN-(2,6-dimethylphenyl)-N-(2-furoyl)alaninate. Journal of Crystallographic and Spectroscopic Research 15, 387–397 (1985). https://doi.org/10.1007/BF01160730

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