Abstract
The crystal structure of Pd(N-PropIm)2Cl2 has been determined from X-ray data collected by counter methods. The compound crystallizes in the monoclinic space groupP21/n with four molecules per unit cell, the dimensions of which area=14.554(5),b=8.204(2),c=14.860(3) Å,β=115.63(2)°. Full-matrix least-squares refinement gave a final R value of 0.0263 for 1913 independent observed reflections. The Pd atom is four-coordinated and is surrounded in atrans square planar fashion by two N atoms of the imidazole groups and by two Cl ions.
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Belletti, D., Ugozzoli, F., Cantoni, A., and Pasquinelli, G. (1979) Gestione on line di diffrattometro a cristallo singolo Siemens AED con sistema General Automation Jumbo 220, Centro di Studio per la Strutturistica Diffrattometrica del CNR. Internal Reports 1, 2, 3, University of Parma, Italy.
Biddau, M., Massacesi, M., Ponticelli, G., Devoto, G., and Zakharova, I. A. (1983)Polyhedron,2, 1261.
Binamira-Soriaga, E., Lundeen, M., and Seff, K. (1979)J. Cryst. Mol. Struc. 9, 67.
Constable, A., McDonald, W. S., and Shaw, B. L. (1979a)J. Chem. Soc. Dalton Trans., 496.
Constable, A., McDonald, W. S., and Shaw, B. L. (1979b)J. Chem. Soc. Dalton Trans., 1109.
Hassner, A., Bunnell, C. A., and Haltiwanger, K. (1978)J. Org. Chem. 43, 57.
International Tables for X-ray Crystallography (1974) Vol. IV (Kynoch Press, Birmingham, England).
Johnson, C. K. (1965)Ortep, Report ORNL-3794, Oak Ridge National Laboratory, Tennessee.
Khare, G. P., Little, R. G., Veal, J. T., and Doedens, R. J. (1975)Inorg. Chem. 14, 2475.
Kuz'mina, L. G., and Struchkov, Yu. T. (1979)Cryst. Struct. Commun. 8, 715.
Lanfredi, A. M., Tiripicchio, A., Natile, G., Gasparrini, F., and Galli, B. (1979)Cryst. Struct. Commun. 8, 611.
Lehmann, M. S., and Larsen, F. K. (1974)Acta Cryst. A 30, 580.
Little, R. G., and Doedens, R. J. (1973)Inorg. Chem. 12, 537.
Nardelli, M. (1983)Comput. Chem. 7, 95.
Natile, G., Gasparrini, F., Galli, B., Lanfredi, A. M., and Tiripicchio, A. (1980)Inorg. Chim. Acta 44, L29.
Navarro-Ranninger, M. C., Martinez-Carrera, S., and Garcia-Blanco, S. (1983a)Acta Cryst. C 39, 186.
Navarro-Ranninger, M. C., Martinez-Carrera, S., and Garcia-Blanco S. (1983b)Acta Cryst. C 39, 188.
Sheldrick, G. M. (1976)Shelx: A System of Computer Programs for X-ray Structure Determination.
Sinn, E., Flynn, C. M., Jr., and Martin, R. B. (1977)Inorg. Chem. 16, 2403.
Ugozzoli, F. (1983)Assorb: A Program for Walker and Stuart's Absorption Correction, University of Parma, Italy.
Walker, N., and Stuart, D. (1983)Acta Cryst. A 39, 158.
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Ianelli, S., Pelizzi, G., Vitali, F. et al. Crystal and molecular structure oftrans-dichlorobis(N-propylimidazole)palladium(II). Journal of Crystallographic and Spectroscopic Research 15, 351–358 (1985). https://doi.org/10.1007/BF01160727
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DOI: https://doi.org/10.1007/BF01160727