Conclusions
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1.
X-ray diffraction analysts and low-temperature DTA have confirmed the formation of the unstable rubidium hexachlorocerate(IV) which is easily hydrolyzed with the formation of Ce(III) derivatives.
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2.
It has been established that the Rb and Cs hexachlorocerates are isomorphous.
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3.
The preparation of the hexachlorocerates(IV) of Li, Na, and K was unsuccessful (according to the low-temperature data).
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Literature cited
A. J. Grant and C. James, J. Am. Chem. Soc.,37, 2652 (1915).
N. Ya. Turova and A. V. Novoselova, Zh. Neorg. Khim.,24, 1724 (1979).
J. Koppel, Z. Anorg. Allgem. Chem.,18, 305 (1898).
A. Brandt, Dissertation [in Russian], Moscow (1981).
L. I. Martynenko, Nauchn. Dokl. Vysshei Sh. Ser. Khim. Khim. Tekhnol.,4, 718 (1958).
Yu. M. Kiselev, A. Brandt, and L. I. Martynenko, USSR Inventor's Certificate No. 835064; Byull. Izobret., No. 20, 145 (1981).
Yu. M. Kiselev, A. Brandt, L. I. Martynenko, and V. I. Spitsyn, Dokl. Akad. Nauk SSSR,246, 879 (1979).
V. M. Potapova (translator), Organicum [Russian translation], Mir, Moscow (1979), Vol. 1, p. 46.
V. I. Spitsyn, L. I. Martynenko, Yu. M. Kiselev, and A. Brandt, Abstracts of papers presented at the XII. Mendeleev Conference on General and Applied Chemistry, Baku (1981), Vol. 1, p. 109.
T. Kaatz and M. Marcovich, Acta Crystallogr.,21, 1011 (1966).
Yu. M. Kiselev and A. I. Popov, Zh. Neorg. Khim.,28, 348 (1983).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 7–11, January, 1985.
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Kiselev, Y.M., Filatov, I.Y., Popov, A.I. et al. Existence of hexachlorocerates(IV) of alkali metals. Russ Chem Bull 34, 1–5 (1985). https://doi.org/10.1007/BF01157317
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DOI: https://doi.org/10.1007/BF01157317