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Structural and spectroscopic properties of N-benzenesulphonylglycine complexes with copper (II)

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Abstract

In this paper are reported structural and spectroscopic properties of (N-benzenesulphonylglycinato) triaquacopper (II) (complex I) and dipotassium bis (N-benzenesulphonylglycinato) cuprate (II) (complex II). The crystals of (I) are monoclinic, space groupP21/c,Z=4, withα=12.736(4),b=10.292(3),c=10.402(3) Å,β=109.41(2)° while those of complex (II) are orthorhombic, space groupPbca, witha=23.333(8),b=10.508(4),c=16.989(5) Å. In both complexes the aminoacid molecules act as bidentatevia carboxylic oxygen and the amide nitrogen atom; in (I) three water molecules complete the coordination to tetragonal pyramidal, while in (II) coordination is square planar, tetrahedrally distorted involving two ligand molecules. The structure (I) was refined to a finalR index of 0.0596 and (II) toR=0.0466.

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Authors and Affiliations

  1. Istituto di Chimica Generale ed Inorganica, Centro di Studio per la Strutturistica Diffrattometrica del CNR, Viale delle Scienze, I-43100, Parma, Italy

    L. P. Battaglia, A. Bonamartini Corradi & G. Pelosi

  2. Dipartimento di Chimica, via Campi 183, I-41100, Modena, Italy

    L. Menabue, M. Saladini & M. Sola

  3. Istituto di Chimica, Facoltà di Medicina Veterinaria, via Gentile, I-70126, Bari, Italy

    G. Marcotrigiano & P. Morini

Authors
  1. L. P. Battaglia
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  2. A. Bonamartini Corradi
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  3. G. Pelosi
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  4. L. Menabue
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  5. M. Saladini
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  6. M. Sola
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  7. G. Marcotrigiano
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  8. P. Morini
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Battaglia, L.P., Corradi, A.B., Pelosi, G. et al. Structural and spectroscopic properties of N-benzenesulphonylglycine complexes with copper (II). Journal of Crystallographic and Spectroscopic Research 21, 313–319 (1991). https://doi.org/10.1007/BF01156083

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  • DOI: https://doi.org/10.1007/BF01156083

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