Abstract
A polyborosilazane, which is a precursor of ceramic fibre, was synthesized from perhydropolysilazane and trimethyl borate. The polyborosilazane was dry-spun and then pyrolysed to produce amorphous Si-B-O-N fibre. The Si-B-O-N fibre retained its high tensile strength to higher temperatures (about 1600 °C). The fibre has a density of 2.4 g cm−3, tensile strength of 2.5 GPa and an elastic modulus of 180 GPa.
Similar content being viewed by others
References
O. Funayama, M. Arai, Y. Tashiro, H. Aoki, T. Suzuki, K. Tamura, H. Nishii andT. Isoda,J. Ceram. Soc. Jpn 98 (1990) 104.
B. G. Penn, F. E. Ledbetter III,J. M. Clemons andJ. G. Daniels,J. Appl. Polym. Sci. 27 (1982) 3751.
G. E. Legrow, T. F. Lim, J. Lipowitz andR. S. Reaoch,Am. Ceram. Soc. Bull. 66 (1987) 363.
S. Yajima, J. Hayashi andM. Omori,Chem. Lett. (1975) 931.
K. Okamura, M. Sato, Y. Hasegawa andT. Amano,ibid. (1984) 2059.
T. Yamamura, T. Ishikawa, M. Shibuya, T. Hisayuki andK. Okamura,J. Mater. Sci. 23 (1988) 2589.
O. Funayama, T. Kato, Y. Tashiro andT. Isoda,J. Am. Ceram. Soc. 76 (1993) 717.
H. J. Campbell-Ferguson andE. V. A. Ebsworth,J. Chem. Soc. A (1966) 1508.
D. Seyferth, G. Wiseman andC. Prud'Homme,J. Am. Ceram. Soc. 66 (1983) C-13.
C. N. R. Rao, in “Chemical Applications of Infrared Spectro-scopy” (Academic Press, New York, 1963) p. 125.
K. R. Carduner, R. O. Carter III,M. E. Milberg andG. M. Crosbie,Anal. Chem. 59 (1987) 2794.
J. Lipowitz, H. A. Freeman, R. T. Chen andE. R. Prack,Adv. Ceram. Mater. 2 (1987) 121.
J. Lipowitz, J. A. Rabe, L. K. Frevel andR. L. Miller,J. Mater. Sci. 25 (1990) 2118.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Funayama, O., Nakahara, H., Tezuka, A. et al. Development of Si-B-O-N fibres from polyborosilazane. J Mater Sci 29, 2238–2244 (1994). https://doi.org/10.1007/BF01154704
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01154704