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Assessment of oxygen in silicon carbide fibres

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Abstract

Five different types of SiC fibre produced by chemical vapour deposition were analysed using Auger electron spectroscopy (AES), scanning electron microscopy (SEM) and X-ray (WDX) analysis. Fibres studied include SCS0, SCS6, Sigma SM1240 and two types of SiC fibres denoted SAM1 and SAM2, produced in the Commonwealth of Independent States (Ukraine, former USSR). Fibres were fracturedin situ in the Auger spectrometer. For each fibre, the oxygen, carbon and silicon yields were measured and qualitative assessment of oxygen was performed. Results suggest that the SCS0 fibre contains less oxygen than other SiC fibres. It was revealed that the SAM1 fibre (120 μm diameter) has a duplex SiC and carbon coating deposited over a 20 μm tungsten core prior to the main SiC deposition, to decouple mechanically the tungsten core from the main SiC deposition.

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References

  1. P. R. Smith andF. H. Froes,J. Metals 36(3) (1984) 19.

    Google Scholar 

  2. W. A. Zdaniewski andH. P. Kirchner,J. Am. Ceram. Soc. 70 (1987) 548.

    Google Scholar 

  3. E. A. Gulbransen, K. F. Andrew andF. A. Brassart,J. Electrochem. Soc. 113 (1966) 1311.

    Google Scholar 

  4. A. G. Turnbull andM. W. Wadey, “CSIRO Thermochemistry System, Version V”, Institute of Mineral, Energy and Construction, Port Melbourne, Victoria, Australia (1993).

    Google Scholar 

  5. F. E. Wawner, in “Fiber reinforcement for composite materials”, Composite Materials Series, edited by A. R. Bunsell, Vol. 2 (Elsevier, 1988) pp. 371–425.

  6. X. J. Ning andP. Pirouz J. Mater. Res. 6 (1991) 2234.

    Google Scholar 

  7. S. R. Nutt andF. E. Wawner,J. Mater. Sci. 20 (1985) 1953.

    Google Scholar 

  8. F. E. Wawner, A. Y. Teng andS. R. Nutt,SAMPE Q. April (1983) 39.

  9. D. Imeson andA. H. Grace, “BP Metal Composites”, Sunbury, UK Report 138141 (1992).

  10. A. M. Ritter, F. Clark andP. Dupree, in “Light weight alloys for aerospace applications”, edited by E. W. Lee and N. J. Kim (TMS, Warrendale, PA, 1991) pp. 403–12.

    Google Scholar 

  11. G. Das,Metall. Trans. 21A (1990) 1571.

    Google Scholar 

  12. W. Wei,J. Mater. Sci. 27 (1992) 1801.

    Google Scholar 

  13. Idem, in “Fundamental relationships between microstructure and mechanical properties of metal matrix composites”, edited by P. K. Liaw and M. N. Gungor (AIME, Warrendale, PA, 1990) pp. 353–60.

    Google Scholar 

  14. J. D. Casey andJ. D. Geller, Research Report, Textron Speciality Materials, Lowell, MA (1992).

  15. H. Debolt andT. Henze, US Pat. 4068 037, January 1978.

  16. D. Martineau, P. Martineau, M. Lahaye, R. Pailler, R. Naslain, M. Couzi andF. Creuge,J. Mater. Sci. 19 (1984) 2731.

    Google Scholar 

  17. D. Upadhyaya, C. M. Ward-Close, P. Tsakiropoulos andF. H. Froes,Mater. Sci. Technol. 10 (1994) 887.

    Google Scholar 

  18. R. A. Shatwell, private communications, DRA Sigma, RAE Farnborough, UK (1993).

  19. L. M. Ivanova andA. A. Pletyushkin, in “Silicon carbide”, research report, edited by I. N. Frantsevich, translated from Russian by Simon Lyse (Consultants Bureau, NY, 1970) pp. 116–21.

    Google Scholar 

  20. D. Upadhyaya andF. H. Froes, unpublished research (1994).

  21. R. A. Mackay,Scripta Metall. Mater. 167 (1990) 167.

    Google Scholar 

  22. F. E. Wawner andD. B. Gundel,SAMPE Q. 23 April (1992) 13.

    Google Scholar 

  23. R. R. Kieschke, R. E. Somekh andT. W. Clyne,Acta. Metall. Mater. 39 (1992) 427.

    Google Scholar 

  24. C. M. Warwick, R. R. Kieschke andT. W. Clyne,ibid. 39 (1992) 437.

    Google Scholar 

  25. S. M. Jeng andJ. M. Yang,J. Mater. Res. 8 (1993) 905.

    Google Scholar 

  26. D. Upadhyaya, R. Brydson, C. M. Ward-Close, P. Tsakiropoulos andF. H. Froes,Mater. Sci. Technol. 10 (1994) 797.

    Google Scholar 

  27. Z. X. Guo, B. Derby andB. Canter,J. Microsc. 169 (1993) 279.

    Google Scholar 

  28. M. A. Baker andP. Tsakiropoulos,Surf. Interface. Anal. 20 (1993) 589.

    Google Scholar 

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Upadhyaya, D., Froes, F.H., Watts, J.F. et al. Assessment of oxygen in silicon carbide fibres. J Mater Sci 30, 3839–3846 (1995). https://doi.org/10.1007/BF01153943

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  • DOI: https://doi.org/10.1007/BF01153943

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