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Negative catalysis by transition-metal salts in oxidation reactions of tertiary aliphatic amines

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Negative catalysis by transition metal salts is realized in radical-chain reactions for the oxidation of dimethylaminoethyl methacrylate, dimethylaminoethy1 propionate, and dime thylbutylamine.

  2. 2.

    The rate constants for the reaction of the peroxide radicals of these tertiary amines with manganese and copper acetates at 50° were measured.

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Literature cited

  1. E. M. Pliss, A. L. Aleksandrov, and M. M. Mogilevich, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 1441.

  2. G. A. Kovtun and A. L. Aleksandrov, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 1274.

  3. A. L. Aleksandrov and E. T. Denisov, Izv. Akad. Nauk SSSR, Ser. Khim.,1969, 1652.

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  10. G. A. Kovtun, G. V. Ponomarev, and A. L. Aleksandrov, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 320.

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Authors and Affiliations

  1. Division of Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    E. M. Pliss & A. L. Aleksandrov

  2. Yaroslavl Polytechnic Institute, USSR

    E. M. Pliss & A. L. Aleksandrov

Authors
  1. E. M. Pliss
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  2. A. L. Aleksandrov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 214–216, January, 1978.

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Pliss, E.M., Aleksandrov, A.L. Negative catalysis by transition-metal salts in oxidation reactions of tertiary aliphatic amines. Russ Chem Bull 27, 187–189 (1978). https://doi.org/10.1007/BF01153240

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  • DOI: https://doi.org/10.1007/BF01153240

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