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Participation of nitroxyl radical in oxidation of aldehyde and alcohol groups in 3-imidazoline-1-oxyl

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the presence of an equimolar amount of alkali the aldehyde group of 4-formyl-2, 2,5,5-tetramethyl-3-imidazoline-1-oxyl is oxidized by the nitroxyl radical to the carboxyl group, whereas the alcohol group of 4-hydroxymethyl-2,2,5,5-tetramethyl-3-imidazoline-1-oxyl is oxidized to the carboxyl group in the presence of excess alkali.

  2. 2.

    In a neutral medium the alcohol group of 4-(1-hydroxyethyl)-2,2,5,5-tetramethyl-3-iraidazoline-1 oxyl is oxidized by the nitroxyl radical to the keto group.

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Literature cited

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Authors and Affiliations

  1. Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    I. A. Grigor'ev & L. B. Volodarskii

Authors
  1. I. A. Grigor'ev
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  2. L. B. Volodarskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 208–210, January, 1978.

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Grigor'ev, I.A., Volodarskii, L.B. Participation of nitroxyl radical in oxidation of aldehyde and alcohol groups in 3-imidazoline-1-oxyl. Russ Chem Bull 27, 182–184 (1978). https://doi.org/10.1007/BF01153238

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  • DOI: https://doi.org/10.1007/BF01153238

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