Conclusions
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1.
We have prepared the first perfluorinated sultine and sulfoxylate ester by the photochemical reaction of hexafluorobutadiene and SO2.
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2.
The sultine isomerizes to the sulfoxylate ester.
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3.
The perfluorinated sultine and sulfoxylate ester readily decompose to form a mixture of difluoromaleyl difluoride and difluorofumaryl difluoride.
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Preliminary report [1].
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 163–171, January, 1978.
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Kaz'mina, N.B., Knynyants, I.L., Mysov, E.I. et al. Photochemical reaction of sulfur dioxide with hexafluorobutadiene. Russ Chem Bull 27, 142–149 (1978). https://doi.org/10.1007/BF01153227
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DOI: https://doi.org/10.1007/BF01153227