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Two pathways for the protolysis of 1-(alkythio)-1-buten-3-ynes and the effect of cis-trans isomerism

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

We have used a spectrophotometric method to examine the kinetics of the hydrolysis of 1-(alkylthio)-1-buten-3-ynes to (alkylthio)butenones and acetoacetaldehyde; the rate of reaction depends markedly on the reactant configuration.

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Literature cited

  1. A. N. Khudyakova, A. N. Volkov, B. A. Trofimov, L. V. Mametova, and R. N. Khudyakova, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 1975.

  2. E. N. Prilezhaeva, G. S. Vasil'ev, and V. V. Petrov, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 2217.

  3. B. A. Trofimov, A. S. Atavin, and O. N. Vylegzhanin, Reakts. Sposobn. Org. Soedin.,5, 441 (1968).

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    A. N. Volkov, A. N. Khuryakova, R. N. Khudyakova, V. V. Keiko & B. A. Trofimov

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  1. A. N. Volkov
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  2. A. N. Khuryakova
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  3. R. N. Khudyakova
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  4. V. V. Keiko
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  5. B. A. Trofimov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 153–159, January, 1978.

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Volkov, A.N., Khuryakova, A.N., Khudyakova, R.N. et al. Two pathways for the protolysis of 1-(alkythio)-1-buten-3-ynes and the effect of cis-trans isomerism. Russ Chem Bull 27, 133–138 (1978). https://doi.org/10.1007/BF01153225

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  • DOI: https://doi.org/10.1007/BF01153225

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