Conclusions
Addition of molybdenum or iron oxides to PdCl2 increases its catalytic activity in the carbonylation of 2,4-dinitrotoluene by carbon monoxide. Increased pressure increases the yield of 2,4-diisocyanatotoluene to ∼90%.
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B. K. Nefedov and V. I. Manov-Yuvenskii, Izv. Akad. Nauk SSSR, Ser. Kliim.,1976, 1905.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 113–115, January, 1978.
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Nefedov, B.K., Manov-Yuvenskii, V.I. & Khoshdurdyev, K.O. Influence of molybdenum and iron oxides on the activity of pdcl2 in the carbonylation of 2,4-dinitrotoluene with carbon monoxide. Russ Chem Bull 27, 99–101 (1978). https://doi.org/10.1007/BF01153218
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DOI: https://doi.org/10.1007/BF01153218