Skip to main content
SpringerLink
Log in

Carbonylation of lower olefins in the presence of complexes of BF3 with propionic, acetic, or monochloroacetic acids

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The 3BF3·2CH2C1COOH+BF3-2CH3COOH system effectively catalyzes the selective carbonylation of propylene and n-butylenes. At 95–105°C and a CO pressure of 200 atm, with an equimolar ratio catalyst∶olefin∶ water, propylene or mixed n-butylenes give isobutyric orα-methylbutyric acid in near-quantitative yield.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. B. S. Friedman and S. M. Cotton, J. Org. Chem.,26, 3751 (1961); U.S. Patent No. 3005846 (1959); Chem. Abs.,56, 4623 (1961).

    Google Scholar 

  2. U.S. Patent No. 3632638 (1972); Ref. Zh. Khim., 19N39P (1972); U.S. Patent No. 3663613 (1972); Ref. Zh. Khim., 3N57P (1973); French Patent No. 2135729 (1972); Ref. Zh. Khim., 3N48P (1973).

  3. Y. Takezaki, Y. Fuchigami, H. Teranishi, N. Sugita, and K. Kudo, Bull. Jap. Petrol. Inst.,8, 31 (1966).

    Google Scholar 

  4. S. D. Pirozhkov, K. V. Puzitskii, T. N. Myshenkova, K. G. Ryabova, and Ya. T. Éidus, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 1314.

  5. S. D. Pirozhkov, K. V. Puzitskii, T. N. Myshenkova, K. G. Ryabova, and Ya. T. Éidus, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 1534.

  6. S. D. Pirozhkov, K. V. Puzitskii, T. N. Myshenkova, K. G. Ryabova, and Ya. T. Éidus, Izv. Akad. Nauk SSSR, Ser. Khim.,1977. 817.

  7. Ya. T. Éidus, S. D. Pirozhkov, and K. V. Puzitskii, Zh. Anal. Khim.,22, 1559 (1967).

    Google Scholar 

  8. R. H. Baker and L. E. Linn, J. Am. Chem. Soc.,70, 3722 (1942).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    S. D. Pirozhkov, K. V. Puzitskii, T. N. Myshenkova & K. G. Ryabova

Authors
  1. S. D. Pirozhkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. V. Puzitskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. N. Myshenkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. G. Ryabova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 110–112, January, 1978.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pirozhkov, S.D., Puzitskii, K.V., Myshenkova, T.N. et al. Carbonylation of lower olefins in the presence of complexes of BF3 with propionic, acetic, or monochloroacetic acids. Russ Chem Bull 27, 96–98 (1978). https://doi.org/10.1007/BF01153217

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01153217

Keywords

Search

Navigation